The Influence of Kaolinite and Quartz on Stability of Coal Froths - A Rheology and Structure Study

Kaolinite and quartz are the common gangue minerals found in raw coal; however, their effects on stability of coal froths and subsequent settling of coal flotation products have not been investigated. In this study, in the coal froths batch settling tests, the amount of froth floating on top of water was 275, 325, 355, and 405 mL for coal concentrates generated with 0, 20, 40, and 60 wt % kaolin Q38, respectively, while that was almost the same (300-306 mL) for coal froth concentrates generated with 0, 20, 40, and 60 wt % quartz added in flotation, respectively, which turned out that the kaolinite could increase the stability of coal froth, while quartz could not. To investigate the mechanism, oscillatory rheology and scanning electron microscopy (SEM) were applied. The results of the oscillatory rheology suggested that the structural strength in coal froth was strengthened with the addition of kaolinite. In addition, images of Plateau borders by SEM illustrated that the addition of kaolinite in flotation increased the size of Plateau borders and generated network structures in the Plateau borders. However, as a comparison, the addition of quartz did not cause an obvious change for the oscillatory rheology and SEM results of coal froth. Based on the results, it can be concluded that network structures were generated in the Plateau border of coal froth with the addition of kaolinite, which increased its structural strength and retarded the drainage in froth. As a result, the stability of the coal froth increased.