A low-coordinate iron organoazide complex

被引：4

作者：

Gonzalez, Andres ^{[1
]}

Demeshko, Serhiy ^{[2
]}

Meyer, Franc ^{[2
]}

Werncke, C. Gunnar ^{[1
]}

机构：

[1] Philipps Univ Marburg, Hans Meerwein Str 4, D-35032 Marburg, Germany

[2] Univ Gottingen, Inst Inorgan Chem, Tammannstr 4, D-37077 Gottingen, Germany

来源：

CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 77期

关键词：

SPECIES RELEVANT; COPPER; REACTIVITY; CLEAVAGE; FE(II); CO(II);

D O I：

10.1039/d3cc03765g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A labile organoazide iron complex is reported. Under ambient conditions, the azide adduct is subject to a dissociation equilibrium in solution, yet also undergoes intramolecular C-H bond amination. Single-crystal irradiation of the azide at 80 K leads to partial N2-extrusion and formation of a putative imido iron intermediate, which was computationally identified as a highly covalent {FeNR}8 species. The isolation and behaviour of a labile iron organoazide adduct is reported.

引用

页码：11532 / 11535

页数：4

共 50 条

[1] Nitrogenase and low-coordinate iron.
Smith, JM
Holland, PL
Lachicotte, RJ
Lukat-Rodgers, G
Rodgers, KR
Cundari, TR
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2003, 226 : U681 - U681
[2] Synthesis and magnetic characterization of a dinuclear complex of low-coordinate iron(II)
Moseley, Ian P.
Lin, Chun-Yi
Zee, David Z.
Zadrozny, Joseph M.
POLYHEDRON, 2020, 175
[3] INOR 797-Reactivity of a low-coordinate iron hydride complex
Yu, Ying
Smith, Jeremy M.
Brennessel, William W.
Holland, Patrick L.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 232
[4] Stepwise reduction of dinitrogen bond order by a low-coordinate iron complex
Smith, JM
Lachicotte, RJ
Pittard, KA
Cundari, TR
Lukat-Rodgers, G
Rodgers, KR
Holland, PL
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (37) : 9222 - 9223
[5] Studies of low-coordinate iron dinitrogen complexes
Smith, JM
Sadique, AR
Cundari, TR
Rodgers, KR
Lukat-Rodgers, G
Lachicotte, RJ
Flaschenriem, CJ
Vela, J
Holland, PL
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (03) : 756 - 769
[6] Studies of low-coordinate iron models of nitrogenase
Vargas, W
Vela, J
Lees, N
Flaschenriem, C
Hoffman, B
Holland, PL
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 230 : U2056 - U2058
[7] N=N bond cleavage by a low-coordinate iron(II) hydride complex
Smith, JM
Lachicotte, RJ
Holland, PL
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (51) : 15752 - 15753
[8] A Bidentate Carbene Ligand Stabilizes a Low-Coordinate Iron(0) Carbonyl Complex
Hickey, Anne K.
Lee, Wei-Tsung
Chen, Chun-Hsing
Pink, Maren
Smith, Jeremy M.
ORGANOMETALLICS, 2016, 35 (17) : 3069 - 3073
[9] Synthesis and Reactivity of a Low-Coordinate Iron(II) Hydride Complex: Applications in Catalytic Hydrodefluorination
Hein, Nicholas M.
Pick, Fraser S.
Fryzuk, Michael D.
INORGANIC CHEMISTRY, 2017, 56 (23) : 14513 - 14523
[10] Low-coordinate iron complexes as synthetic models of nitrogenase
Holland, PL
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 2005, 83 (04): : 296 - 301

← 1 2 3 4 5 →