Nickel-Catalyzed Cross-Electrophile Coupling of Aryl Phosphates with Aryl Bromides

被引：26

作者：

Ren, Jing-Ao ^{[1
]}

Chen, Xue ^{[1
]}

Gui, Chao ^{[1
]}

Miao, Chengping ^{[2
]}

Chu, Xue-Qiang ^{[1
]}

Xu, Hao ^{[1
]}

Zhou, Xiaocong ^{[1
,2
]}

Ma, Mengtao ^{[3
]}

Shen, Zhi-Liang ^{[1
]}

机构：

[1] Nanjing Tech Univ, Tech Inst Fluorochem TIF, Inst Adv Synth, Sch Chem & Mol Engn, Nanjing 211816, Peoples R China

[2] Jiaxing Univ, Coll Biol Chem Sci & Engn, 118 Jiahang Rd, Jiaxing 314001, Peoples R China

[3] Nanjing Forestry Univ, Coll Sci, Nanjing 210037, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2023年 / 365卷 / 15期

基金：

中国国家自然科学基金;

关键词：

cross-electrophile coupling; nickel; aryl phosphate; magnesium; lithium chloride; biaryl; NEGISHI COUPLINGS; DIRECT INSERTION; ALKYL-HALIDES; REAGENTS; ALKENYL; LIGAND; REACTIVITY; ACCESS;

D O I：

10.1002/adsc.202300663

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A step-economical and operationally simple nickel-catalyzed cross-electrophile coupling of aryl phosphates with aryl bromides through C-O bond cleavage, which precluded the employment of relatively moisture-labile and unreadily available organometallics, was developed. The reaction proceeded smoothly in the presence of magnesium turnings and lithium chloride in THF to afford the corresponding biaryls in moderate to good yields with reasonable functionality tolerance.

引用

页码：2511 / 2515

页数：5

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