Ruthenium(III) Chloride as an Efficient Catalyst for the Selective Oxidation of Fatty Alcohols to Aldehydes

被引：2

作者：

Nunheim, Nelly F. ^{[1
]}

Kaiser, Bianca ^{[1
]}

Thiel, Werner R. ^{[1
]}

机构：

[1] Tech Univ Kaiserslautern, Fachbereich Chem, Erwin Schrodinger Str 54, D-67663 Kaiserslautern, Germany

来源：

CHEMISTRYSELECT | 2023年 / 8卷 / 12期

关键词：

alcohol oxidation; catalysis; fatty aldehyde; ruthenium chloride; trimethylamine N-oxide; DESIGN; COMPLEX; KETONES;

D O I：

10.1002/slct.202300346

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The oxidation of a series of fatty alcohols to yield the corresponding aldehydes is performed using RuCl3 center dot(H2O)(x) as a homogeneous catalyst and inexpensive trimethylamine N-oxide (TMAO) as the oxygen source. The reaction conditions were optimized for both high conversion and high selectivity.

引用

页数：5

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