Thermal degradation model of used surgical masks based on machine learning methodology

Background: The COVID-19 pandemic has leveraged facial masks to be one of the most effective measures to prevent the spread of the virus, which thereby has exponentially increased the usage of facial masks that lead to medical waste mismanagements which pose a serious threat to life. Thermal degradation or pyrolysis is an effective treatment method for the used facial mask wastes and this study aims to investigate the thermal degradation of the same.Methods: Predicted the TGA experimental curves of the mask components using a Machine Learning model known as Artificial Neural Network (ANN). Significant findings: Three different parts of the mask namely-ribbon, body, and corner were separated and used for the analysis. The thermal degradation behavior is studied using Thermogravimetric Analysis (TGA) and this is crucial for determining the reactivity of the individual mask components as they are subjected to a range of temperatures. Using the curves obtained from TGA, kinetic parameters such as Activation energy (E) and Pre -exponential factor (A) were estimated using the Coats-Redfern model-fitting method. Using the determined ki-netic parameters, thermodynamic quantities such as a change in Enthalpy (Delta H), Entropy (Delta S), and Gibbs-Free energy (Delta G) were also calculated. Since TGA is a costly and time-consuming process, this study attempted to predict the TGA experimental curves of the mask components using a Machine Learning model known as Arti-ficial Neural Network (ANN). The dataset obtained at a heating rate of 10 degrees C/min was used to train the 3 different neural networks corresponding to the mask components and it showed an excellent agreement with experimental data (R2 > 0.99). Through this study, a complex chemical process such as thermal degradation was modelled using Machine Learning based on available experimental parameters without delving into the intricacies and complexities of the process.