Surface-Modified In2O3 for High-Throughput Screening of Volatile Gas Sensors in Diesel and Gasoline

被引:1
作者
Zhang, Deqi [1 ,2 ]
Guo, Shenghui [1 ,2 ]
Gao, Jiyun [2 ]
Yang, Li [1 ,2 ]
Zhu, Ye [2 ]
Ma, Yanjia [2 ]
Hou, Ming [2 ]
机构
[1] Kunming Univ Sci & Technol, State Key Lab Complex Nonferrous Met Resources Cle, Kunming 650093, Peoples R China
[2] Kunming Univ Sci & Technol, Fac Met & Energy Engn, Kunming 650093, Peoples R China
基金
中国国家自然科学基金;
关键词
high-throughput screening; surface modification; In2O3; gas sensor; fuel volatiles; TEMPERATURE;
D O I
10.3390/ma16041517
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this paper, with the help of the method of composite materials science, parallel synthesis and high-throughput screening were used to prepare gas sensors with different molar ratios of rare earths and precious metals modified In2O3, which could be used to monitor and warn the early leakage of gasoline and diesel. Through high-throughput screening, it is found that the effect of rare earth metal modification on gas sensitivity improvement is better than other metals, especially 0.5 mol% Gd modified In2O3 (Gd0.5In) gas sensor has a high response to 100 ppm gasoline (R-a/R-g = 6.1) and diesel (R-a/R-g = 5) volatiles at 250 degrees C. Compared with the existing literature, the sensor has low detection concentration and suitable stability. This is mainly due to the alteration of surface chemisorption oxygen caused by the catalysis and modification of rare earth itself.
引用
收藏
页数:10
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