A prediction model to predict the thermodynamic conditions of gas hydrates

被引:3
|
作者
Sayani, Jai Krishna Sahith [1 ]
English, Niall J. [1 ]
Khan, Muhammad Saad [2 ]
Ali, Abulhassan [3 ]
机构
[1] Univ Coll Dublin, Sch Chem & Bioproc Engn, Dublin D04 V1W8, Ireland
[2] Univ Teknol PETRONAS, CO2 Res Ctr, Seri Iskandar, Perak, Malaysia
[3] Jeddah Univ, Dept Chem Engn, Jeddah, Saudi Arabia
关键词
Gas hydrate; Thermodynamic conditions; EOS; Phase behavior; Prediction modelling; CARBON-DIOXIDE; HYDROGEN STORAGE; ALKYL CHAIN; ENERGY; MEMBRANES; STATE; CO2;
D O I
10.1016/j.chemosphere.2022.137550
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Gas Hydrate modelling has gained huge attention in the past decade due to its increase in usage for various energy as well as environmental applications at an industrial scale. As the experimental approach is highly expensive and time-consuming, modelling is the best way to predict the conditions before the actual applications at industrial scales. The commercial software currently existing uses the equation of states (EOS) to predict the thermodynamic conditions of gas hydrates. But, in certain cases, the prediction by using EOS fails to predict the hydrate conditions accurately. Therefore, there arose a need for an accurate prediction model to estimate the hydrate formation conditions. So, in this work, an accurate prediction model has been proposed to predict the thermodynamic equilibrium conditions of the gas hydrate formation. The performance of prediction accuracy for the proposed model is compared with those of the SRK equation of state and Peng Robinson (PR) Equation of state. It was observed that in most of the cases the proposed model has predicted the thermodynamic conditions more accurately than the PR and SRK equation of state. This work helps in understanding the limitations of EOS for the prediction hydrate conditions. Also, the current work helps in strengthening the conventional statistical modelling technique to predict the hydrate conditions for a broader range.
引用
收藏
页数:7
相关论文
共 50 条
  • [31] Synergistic effect of salts and methanol in thermodynamic inhibition of sII gas hydrates
    Semenov, Anton P.
    Stoporev, Andrey S.
    Mendgaziev, Rais, I
    Gushchin, Pavel A.
    Khlebnikov, Vadim N.
    Yakushev, Vladimir S.
    Istomin, Vladimir A.
    Sergeeva, Dada, V
    Vinokurov, Vladimir A.
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2019, 137 : 119 - 130
  • [32] Features of Heat and Mass Transfer in the Thermodynamic Equilibrium Region of Gas Hydrates
    Koshlak, Hanna
    Ochrymiuk, Tomasz
    ENVIRONMENTAL AND CLIMATE TECHNOLOGIES, 2024, 28 (01) : 695 - 711
  • [33] Application of statistical learning theory for thermodynamic modeling of natural gas hydrates
    Kumari, Anupama
    Madhaw, Mukund
    Majumder, C. B.
    Arora, Amit
    Dixit, Gaurav
    PETROLEUM, 2021, 7 (04) : 502 - 508
  • [34] Phase behavior of gas hydrates in nanoporous materials: Review
    Kim, Daeok
    Lee, Huen
    KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2016, 33 (07) : 1977 - 1988
  • [35] Ionic liquids for the inhibition of gas hydrates. A review
    Ul Haq, Ihtisham
    Qasim, Ali
    Lal, Bhajan
    Zaini, Dzulkarnain B.
    Foo, Khor Siak
    Mubashir, Muhammad
    Khoo, Kuan Shiong
    Vo, Dai-Viet N.
    Leroy, Eric
    Show, Pau Loke
    ENVIRONMENTAL CHEMISTRY LETTERS, 2022, 20 (03) : 2165 - 2188
  • [36] Experimental measurement of phase equilibrium for gas hydrates of refrigerants, and thermodynamic modeling by SRK, VPT and CPA EOSs
    Karamoddin, Maryam
    Varaminian, Farshad
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2013, 65 : 213 - 219
  • [37] Gas separation of flue gas by tetra-n-butylammonium bromide hydrates under moderate pressure conditions
    Hashimoto, Hidenori
    Yamaguchi, Tsutomu
    Kinoshita, Takahiro
    Muromachi, Sanehiro
    ENERGY, 2017, 129 : 292 - 298
  • [38] Thermodynamic model of phase equilibria of tetrabutyl ammonium halide (fluoride, chloride, or bromide) plus methane or carbon dioxide semiclathrate hydrates
    Shi, Ling-li
    Liang, De-qing
    FLUID PHASE EQUILIBRIA, 2015, 386 : 149 - 154
  • [39] Is the Surface of Gas Hydrates Dry?
    Maeda, Nobuo
    ENERGIES, 2015, 8 (06): : 5361 - 5369
  • [40] Analysis of the Techniques for Measuring the Equilibrium Conditions of Gas Hydrates Formation
    Semenov, A. P.
    Mendgaziev, R., I
    Tulegenov, T. B.
    Stoporev, A. S.
    CHEMISTRY AND TECHNOLOGY OF FUELS AND OILS, 2022, 58 (04) : 628 - 636