Insights into the tribological behavior of choline chloride-urea and choline chloride-thiourea deep eutectic solvents

被引：37
作者：
Li, Yuting [1 ]
Li, Yuan [1 ]
Li, Hao [1 ]
Fan, Xiaoqiang [1 ]
Yan, Han [1 ]
Cai, Meng [2 ]
Xu, Xiaojun [1 ]
Zhu, Minhao [1 ,2 ]
机构：
[1] Southwest Jiaotong Univ, Sch Mat Sci & Engn, Key Lab Adv Technol Mat, Minist Educ, Chengdu 610031, Peoples R China
[2] Southwest Jiaotong Univ, Sch Mech Engn, Tribol Res Inst, Chengdu 610031, Peoples R China
来源：
FRICTION | 2023年 / 11卷 / 01期
基金：
中国国家自然科学基金;
关键词：
deep eutectic solvents (DESs); tribo-chemical film; von Mises stress; lubrication mechanism; RAY PHOTOELECTRON-SPECTROSCOPY; IRON; XPS; CATALYSTS; GLYCEROL; CATIONS; OXYGEN; POINT; SO2; ZNS;
D O I：
10.1007/s40544-021-0575-4
中图分类号：
TH [机械、仪表工业];
学科分类号：
0802 ;
摘要：
Deep eutectic solvents (DESs) have been considered as novel and economic alternatives to traditional lubricants because of their similar physicochemical performance. In this study, choline chloride (ChCl) DESs were successfully synthesized via hydrogen-bonding networks of urea and thiourea as the hydrogen bond donors (HBDs). The as-synthesized ChCl-urea and ChCl-thiourea DESs had excellent thermal stability and displayed good lubrication between steel/steel tribo-pairs. The friction coefficient and wear rate of ChCl-thiourea DES were 50.1% and 80.6%, respectively, lower than those of ChCl-urea DES for GCr15/45 steel tribo-pairs. However, for GCr15/Q45 steel, ChCl-urea DES decreased the wear rate by 85.0% in comparison to ChCl-thiourea DES. Under ChCl-thiourea DES lubrication, the tribo-chemical reaction film composed of FeS formed at the interfaces and contributed to low friction and wear. However, under high von Mises stress, the film could not be stably retained and serious wear was obtained through direct contact of friction pairs. This illustrated that the evolution of the tribo-chemical reaction film was responsible for the anti-friction and anti-wear properties of the DESs.
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收藏
页码：76 / 92
页数：17
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