Solubilities of Components in the Сa(ClO3)2•NH4Сl-H2O System

被引:2
|
作者
Rakhmonov, O. O. [1 ]
Sidikov, A. A. [1 ]
Shukurov, Zh. S. [1 ]
Togasharov, A. S. [1 ]
机构
[1] Acad Sci Uzbek, Inst Gen & Inorgan Chem, Tashkent 100170, Uzbekistan
关键词
calcium chlorate; ammonium chloride; solubility; diagram; composition-property;
D O I
10.1134/S0036023623602271
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The & Scy;a(ClO3)(2)center dot NH4 & Scy;l-H2O system has been studied in its constituent binary systems and seven inner sections, and its polythermal solubility diagram has been plotted in the range of temperatures from-42.5 to 87.5 degrees & Scy;. The solubility diagram features the crystallization fields of ice; calcium chlorate hexahydrate, tetrahydrate, and dihydrate; and ammonium chloride. Three ternary points exist in the system. The system belongs to the complex eutonic type; its components retain their individuality and show good solubility in water. In the [40% & Scy;a(ClO3)(2) + 60% H2O]-[NH4 & Scy;l] section of the studied system, variations in crystallization temperature, viscosity, density, pH, and refractive indices of the solution have been determined. The thus-obtained results have been used to plot the composition-property diagram of the [40% & Scy;a(ClO3)(2) + 60% H2O]-[NH4 & Scy;l] section of the & Scy;a(ClO3)(2)center dot NH4 & Scy;l-H2O system.
引用
收藏
页码:1829 / 1833
页数:5
相关论文
共 50 条
  • [21] SUPERSATURATION OF SOLUTIONS IN THE SYSTEM (NH4)2HPO4-NH4H2PO4-NH4NO3-H2O .3.
    KASHCHEEVA, IA
    KAGANSKII, IM
    KORDON, IV
    JOURNAL OF APPLIED CHEMISTRY OF THE USSR, 1980, 53 (07): : 1168 - 1171
  • [22] Thermodynamic analysis on reaction behaviors of silicates in (NH4)2WO4-(NH4)2CO3-NH3-H2O system
    Li, Xiao-bin
    Shen, Lei-ting
    Tong, Xiao-yi
    Qi, Tian-gui
    Liu, Gui-hua
    Zhou, Qiu-sheng
    Peng, Zhi-hong
    TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA, 2018, 28 (11) : 2342 - 2350
  • [23] (NH4)2SIF6-NH4H2PO4-H2O SYSTEM
    MORGUNOV.EM
    GOLOVINA, VN
    MASLOVA, ND
    ZHURNAL NEORGANICHESKOI KHIMII, 1972, 17 (07): : 2006 - &
  • [24] DOUBLE SALTS OF THE NH4NO3-(NH4)2SO4-H2O SYSTEM
    TURLEJ, J
    PIENIAZEK, T
    PRZEMYSL CHEMICZNY, 1981, 60 (7-8): : 418 - 422
  • [25] (NH4)2CO3-(NH4)2SO4-H2O SYSTEM AT 15-DEGREES-C
    BELYAEV, IN
    GRIGOREVA, EA
    ZHURNAL NEORGANICHESKOI KHIMII, 1979, 24 (10): : 2853 - 2854
  • [26] Equilibrium WO3 concentration in the Ca2+-(NH4)2CO3-(NH4)2 WO4-NH3-H2O system
    Xu, Xiangming
    Li, Xiaobin
    Zhou, Qiusheng
    Qi, Tiangui
    Zhou, Kechao
    Liu, Guihua
    Peng, Zhihong
    CHEMICAL ENGINEERING SCIENCE, 2019, 206 : 156 - 163
  • [27] Dissolving behavior of ammonium paratungstate in (NH4)2CO3-NH3•H2O-H2O system
    Li, Xiao-bin
    Gao, Chun-hui
    Zhou, Jie
    Zhou, Qiu-sheng
    Qi, Tian-gui
    Liu, Gui-hua
    Peng, Zhi-hong
    TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA, 2018, 28 (07) : 1456 - 1464
  • [28] STUDY OF SOLUBILITY IN A NH4NO3-NH4H2PO4-(NH4)2H2P2O7 SYSTEM
    KASHCHEE.IA
    KAGANSKI.IM
    VARLAMOV, ML
    MANAKIN, GA
    ZHURNAL PRIKLADNOI KHIMII, 1973, 46 (07) : 1489 - 1491
  • [29] (NH4)HPO4-NH4H2PO4-K2S2O3-CO(NH2)2-H2O SYSTEM
    BABENKO, AM
    ZHURNAL NEORGANICHESKOI KHIMII, 1987, 32 (08): : 2038 - 2041
  • [30] RECIPROCAL SOLUBILITY IN THE SYSTEM (NH4)2HPO4-(NH4)2SO4-H2O
    CHERNOVA, KS
    KORZH, EV
    ZHURNAL OBSHCHEI KHIMII, 1946, 16 (02): : 171 - 178