Sodium titanate: A proton conduction material for ppb-level NO2 detection with near-zero power consumption

Constrained by the traditional charge transfer sensing mechanism, it is quite challenging to fabricate NO2 sensors that simultaneously exhibit high sensitivity, rapid response/recovery, and low power consumption. Herein, sodium titanate (NTO), a layered material with abundant surface-rooted OH groups (OHR), is demonstrated to be a promising NO2 sensing material. To understand the sensing behavior of NTO, the influences of operating temperature, applied voltage, and relative humidity are investigated, and a novel OHR-enabled proton conduction sensing mechanism is proposed. The sensing process mainly involves selective NO2 adsorption on OHR, thereby lowering the activation energy for proton transportation along the NTO surface. Meanwhile, the moderate intermolecular interaction makes NO2 both easily adsorbed and desorbed at room temperature. Hence, NTO exhibits a highly sensitive, rapid, and fully recoverable response (similar to 5.7-1 ppm NO2 within 3 s), wide detection range (1 ppb-20 ppm), good stability (>2 months), and near-zero power consumption (0.5 nW). Finally, we demonstrate that NTO has an excellent practical indoor/outdoor NO2 sensing ability. This work offers a new pathway to resolve the inherent conflicts in available NO2 sensors by using NTO via the OHR-enabled proton conduction sensing mechanism, which may also provide insight into designing high-performance sensors for other gases.