Metal-Organic Frameworks for the Enhancement of Lithium-Based Batteries: A Mini Review on Emerging Functional Designs

Metal-organic frameworks (MOFs) have played a crucial role in recent advancements in developing lithium-based battery electrolytes, electrodes, and separators. Although many MOF-based battery components rely on their well-defined porosity and controllable functionality, they also boast a myriad of other significant properties relevant to battery applications. In this mini-review, the distinct advantages of MOFs in battery applications are discussed, including using MOFs to 1) scavenge impurities to increase cycling stability, 2) widen the operation temperature range of conventional electrolytes, 3) widen the operation voltage range of common electrolytes, and 4) employ as artificial solid-electrolyte interphases to prevent lithium dendrite growth. Furthermore, subsisting challenges of developing these emerging MOF-based battery technologies are discussed and guidance for shaping the future of this field is given. MOFs possess distinct advantages in scavenging impurities to increase cycling stability, increasing operation temperatures and voltages of common electrolytes, and can be used as artificial solid-electrolyte interphases to prevent lithium dendrite growth. In this mini-review, the emerging battery applications of metal-organic frameworks (MOFs) are outlined, and a perspective of future MOF-based battery technologies is proposed.image