Contrasting response on magnetocaloric effect and refrigeration capacity due to Ni or Mn substitution by Fe in Ni-Mn-In-Co-Fe alloys

被引：8
作者：
Camarillo-Garcia, Juan-Pablo [1 ]
Hernandez-Navarro, Fernando [2 ]
Flores-Zuniga, Horacio [3 ]
Hugo Baltazar-Hernandez, Victor [1 ]
Alvarado-Hernandez, Francisco [1 ]
机构：
[1] Univ Autonoma Zacatecas, Ramon Lopez Velarde 801, Zacatecas 98000, Zacatecas, Mexico
[2] Univ Autonoma San Luis Potosi, Inst Met, Sierra Leona 550,Col Lomas 2a, San Luis Potosi 78210, San Luis Potosi, Mexico
[3] Inst Potosino Invest Cient & Tecnol, Camino Presa San Jose 2055,Col Lomas 4a, San Luis Potosi 78216, San Luis Potosi, Mexico
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 2023年 / 934卷
关键词：
Magnetocaloric effect; Magnetic entropy change; Refrigeration capacity; Heusler alloys; SHAPE-MEMORY ALLOYS; MARTENSITIC-TRANSFORMATION; MAGNETIC-PROPERTIES; TRANSITION; ORDER;
D O I：
10.1016/j.jallcom.2022.167852
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We set the composition of two Ni-Mn-In-Co-Fe alloys as (Ni46.8Fe1.2)Co2Mn36.5In13.5 and Ni48Co2(Mn34.5Fe2) In13.5 in order to display the martensitic transformation near to room temperature. Under a magnetic field change of 5 T the polycrystalline low Co content alloys displayed a large magnetocaloric effect ASMag of 15.5 and 20.0 Jkg-1K-1; and giant refrigeration capacity RCFWHM up to 422 and 292 Jkg-1 for (Ni46.8Fe1.2)Co2Mn36.5In13.5 and Ni48Co2(Mn34.5Fe2)In13.5, respectively. The XRD patterns showed cubic L21 structure with space group 225 in both alloys and via Rietveld refinement negligible differences were found in lattice parameter of 0.598(7) and 0.598(9) nm for (Ni46.8Fe1.2)Co2Mn36.5In13.5 and Ni48Co2(Mn34.5Fe2) In13.5, respectively. Nevertheless, the magnetocaloric response in the alloys exhibited remarkable dissim-ilarities. Whilst the applied magnetic field shifted the martensitic transformation - 3.4 KT-1 in the Ni48Co2(Mn34.5Fe2)In13.5 alloy this sensibility increased up to - 6.8 KT-1 in the (Ni46.8Fe1.2)Co2Mn36.5In13.5 alloy; consequently the span in the Full Width Half Maximum of the ASMag(T) curve was 17 and 32 K, respectively.(c) 2022 Elsevier B.V. All rights reserved.
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页数：6
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