Mechanical, thermal and morphological features of biodegradable crosslinked natural rubber latex- dextrin blends

被引:2
作者
Mathew, Mekha Mariam [1 ]
Panicker, Unnikrishnan G. [1 ]
机构
[1] Natl Inst Technol Calicut, Dept Chem, Polymer Sci & Technol Res Lab, NIT Campus PO, Kozhikode 673601, Kerala, India
关键词
Natural rubber latex; Dextrin; Polymer blend; Biodegradable; MEMBRANES;
D O I
10.1007/s10965-023-03772-w
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Biodegradable crosslinked blends of natural rubber latex (NRL) and dextrin (DXT) have been prepared in various ratios, with cumene hydrogen peroxide (CHP) as the curing agent. Characterization techniques employing infrared spectroscopy, thermogravimetric analysis and X-ray diffraction provide insights into the physico-chemical properties of the blends. The phase morphology and topographical analysis have been done through scanning electron microscopy (SEM) and atomic force microscopy (AFM) examinations respectively. Soil degradation studies, duly assisted with SEM examinations, were performed to confirm the biodegradability of the films. The stress-strain characteristics were analyzed using the Raman spectra. The mechanical properties of the cross-linked blends have been compared with relevant theoretical models. The experimental results for the mechanical properties were subjected to a one-way analysis of variance (ANOVA) using MINITAB software. The optimized crosslinked polymer blend showed biocompatibility with L929 (mouse fibroblast) cells and has been proposed for controlled drug delivery, with tuneable release characteristics.
引用
收藏
页数:17
相关论文
共 47 条
  • [1] Comprehensive experimental investigations and theoretical predictions on the physical properties of natural rubber composites
    Abhisha, Vakkoottil Sivadasan
    Sisanth, Krishanagegham Sidharathan
    Parameswaranpillai, Jyotishkumar
    Pulikkalparambil, Harikrishnan
    Siengchin, Suchart
    Thomas, Sabu
    Stephen, Ranimol
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2022, 139 (47)
  • [2] STRAIN-INDUCED CRYSTALLIZATION OF NATURAL RUBBER: EFFECT OF PROTEINS AND PHOSPHOLIPIDS
    Amnuaypornsri, Sureerut
    Sakdapipanich, Jitladda
    Toki, Shigeyuki
    Hsiao, Benjamin S.
    Ichikawa, Naoya
    Tanaka, Yasuyuki
    [J]. RUBBER CHEMISTRY AND TECHNOLOGY, 2008, 81 (05): : 753 - 766
  • [3] In vitro cytotoxicity evaluation of natural rubber latex film surface coated with PMMA nanoparticles
    Anancharungsuk, Waranya
    Polpanich, Duangporn
    Jangpatarapongsa, Kulachart
    Tangboriboonrat, Pramuan
    [J]. COLLOIDS AND SURFACES B-BIOINTERFACES, 2010, 78 (02) : 328 - 333
  • [4] Controlled degradation and functionalization of natural rubber by ozonolysis in organic solvent
    Banan, Alireza
    Mehdipour, Hossein
    [J]. JOURNAL OF POLYMER RESEARCH, 2021, 28 (09)
  • [5] Structure and properties of polylactide/natural rubber blends
    Bitinis, N.
    Verdejo, R.
    Cassagnau, P.
    Lopez-Manchado, M. A.
    [J]. MATERIALS CHEMISTRY AND PHYSICS, 2011, 129 (03) : 823 - 831
  • [6] Degradation of oxo-biodegradable rubber and its impact on ecosystem services
    Cheng, Acga
    Azhar, Natasya Nabilla Hairon
    Abdullah, Rosazlin
    Lee, Siang Yin
    Ang, Desmond Teck-Chye
    [J]. EUROPEAN POLYMER JOURNAL, 2023, 190
  • [7] Electrical, Mechanical, and Thermal Analysis of Natural Rubber/Polyaniline-Dbsa Composite
    da Silva, Michael Jonas
    Sanches, Alex Otavio
    Malmonge, Luiz Francisco
    Malmonge, Jose Antonio
    [J]. MATERIALS RESEARCH-IBERO-AMERICAN JOURNAL OF MATERIALS, 2014, 17 : 59 - 63
  • [8] Faggio G., 2021, SPECTROSCOPY MAT CHA, P169, DOI DOI 10.1002/9781119698029.CH6
  • [9] Influence type of natural rubber on properties of green biodegradable thermoplastic natural rubber based on poly(butylene succinate)
    Faibunchan, Parisa
    Pichaiyut, Skulrat
    Chueangchayaphan, Wannarat
    Kummerloewe, Claudia
    Venneman, Norbert
    Nakason, Charoen
    [J]. POLYMERS FOR ADVANCED TECHNOLOGIES, 2019, 30 (04) : 1010 - 1026
  • [10] Gbadeyan O. J., 2021, Journal of Engineering Science and Technology Review, V14, P61, DOI [10.25103/jestr.145.08, DOI 10.25103/JESTR.145.08]