Recent advances in visible light-me diate d chemical transformations of enaminones

被引：87

作者：

Han, Yu ^{[1
,2
]}

Zhou, Liyun ^{[1
]}

Wang, Chengyu ^{[2
]}

Feng, Shangti ^{[3
]}

Ma, Rong ^{[2
]}

Wan, Jie-Ping ^{[1
]}

机构：

[1] Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Peoples R China

[2] Linyi Univ, Sch Chem & Chem Engn, Linyi 276000, Peoples R China

[3] Linyi Sanfeng Chem Co Ltd, Linyi 276000, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 2024年 / 35卷 / 02期

基金：

中国国家自然科学基金;

关键词：

Enaminone; Visible light; C -H functionalization; C = C bond cleavage; Cyclization; Multicomponent reactions; METAL-FREE SYNTHESIS; C-H THIOCYANATION; PHOTOREDOX CATALYSIS; BOND-CLEAVAGE; C=C BOND; CASCADE REACTION; DERIVATIVES; ANNULATION; ACCESS; CYCLIZATION;

D O I：

10.1016/j.cclet.2023.108977

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Enaminones, which possesses both the nucleophilic enamine as well as electrophilic enone structures, are well known versatile building blocks in organic synthesis. Meanwhile, visible light-mediated reac-tions have emerged as useful synthetic strategy with enhanced sustainability. Around the last decade, various photochemical transformations of enaminones have been developed to construct cyclic or acyclic compounds. In this review, we describe the recent advances in visible light-mediated chemical transfor-mations of enaminones. Detailed discussion on the reaction mechanism of the related reactions is given to provide guide to the reader. Finally, a summary on the existing challenges and the future outlook towards the development of practical photocatalytic reactions of enaminones is also presented. (c) 2023 Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences.

引用

页数：12

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