Azeotropic dehydrative (solution) polycondensation of lactic acid to polylactic acid (PLA): A in-depth review of an overlooked method for manufacturing PLA

被引:10
作者
Desai, Harsh [1 ]
Mehta, Tejal [2 ]
Shah, Nimish [1 ]
机构
[1] Nirma Univ, Inst Technol, Ahmadabad, India
[2] Nirma Univ, Inst Pharm, Ahmadabad, India
来源
POLYMER-PLASTICS TECHNOLOGY AND MATERIALS | 2023年 / 62卷 / 11期
关键词
Azeotropic polymerization; Lactic acid polymerization; Polylactic acid (PLA) synthesize; Solution polymerization; RING-OPENING POLYMERIZATION; DIRECT CONDENSATION POLYMERIZATION; WEIGHT POLY(L-LACTIC ACID); MOLECULAR-WEIGHT; POLY(LACTIC ACID); MELT POLYCONDENSATION; STABILITY; MECHANISM; INCREASE; LACTATE;
D O I
10.1080/25740881.2023.2209644
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Polylactic acid (PLA) is one of the most promising biopolymers. PLA shows its versatility in biomedical, additive manufacturing, packaging, and many more applications. Its tailorable properties, biocompatibility, and good processibility have attracted researchers. Over the years, the manufacturing of PLA on an industrial scale has grown considerably. Different researchers have reported various methods for PLA synthesize. Ring-opening polymerization (ROP) is a widely used synthesize and commercial manufacturing method. But ROP is quite an expensive method, so it limits the application of PLA in many products. One of the most unexplored methods for PLA synthesize is azeotropic dehydrative polycondensation or solution polymerization. In this study, all methods are compiled and compared on various aspects.
引用
收藏
页码:1394 / 1402
页数:9
相关论文
共 60 条
[1]   BASIC PROPERTIES OF POLYLACTIC ACID PRODUCED BY THE DIRECT CONDENSATION POLYMERIZATION OF LACTIC-ACID [J].
AJIOKA, M ;
ENOMOTO, K ;
SUZUKI, K ;
YAMAGUCHI, A .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1995, 68 (08) :2125-2131
[2]   Effect of solid-state polymerization on the structure and properties of mechanically recycled poly(lactic acid) [J].
Beltran, Freddys R. ;
Climent-Pascual, Esteban ;
de la Orden, Maria U. ;
Martinez Urreaga, Joaquin .
POLYMER DEGRADATION AND STABILITY, 2020, 171
[3]   Critical review of FDM 3D printing of PLA biocomposites filled with biomass resources, characterization, biodegradability, upcycling and opportunities for biorefineries [J].
Bhagia, Samarthya ;
Bornani, Kamlesh ;
Agrawal, Ruchi ;
Satlewal, Alok ;
Durkovic, Jaroslav ;
Lagana, Rastislav ;
Bhagia, Meher ;
Yoo, Chang Geun ;
Zhao, Xianhui ;
Kunc, Vlastimil ;
Pu, Yunqiao ;
Ozcan, Soydan ;
Ragauskas, J. Arthur .
APPLIED MATERIALS TODAY, 2021, 24
[4]   Zinc bis-pyrrolide-imine complexes: Synthesis, structure and application in ring-opening polymerization of rac-actide [J].
Caovilla, Alessandra ;
Penning, Juliana S. ;
Pinheiro, Adriana C. ;
Hild, Frederic ;
Stieler, Rafael ;
Dagorne, Samuel ;
Casagrande, Osvaldo L., Jr. ;
Gil, Marcelo P. .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2018, 863 :95-101
[5]  
Carothers W.H., 1932, J. Am. Chem. Soc, V54, P761, DOI DOI 10.1021/JA01341A046
[6]   Enzymatic synthesis of poly-l-lactide and poly-l-lactide-co-glycolide in an ionic liquid [J].
Chanfreau, Sebastien ;
Mena, Maria ;
Porras-Dominguez, Jaime R. ;
Ramirez-Gilly, Mariana ;
Gimeno, Miquel ;
Roquero, Pedro ;
Tecante, Alberto ;
Barzana, Eduardo .
BIOPROCESS AND BIOSYSTEMS ENGINEERING, 2010, 33 (05) :629-638
[7]   Poly(lactic acid) microcapsules: Tailoring properties via solid state polymerization [J].
Chronaki, Konstantina ;
Korres, Dimitrios M. ;
Papaspyrides, Constantine D. ;
Vouyiouka, Stamatina .
POLYMER DEGRADATION AND STABILITY, 2020, 179
[8]  
Dutkiewicz S, 2003, FIBRES TEXT EAST EUR, V11, P66
[9]   Enzymatic Ring-Opening Polymerization of Lactones: Traditional Approaches and Alternative Strategies [J].
Engel, Jennifer ;
Cordellier, Alex ;
Huang, Lei ;
Kara, Selin .
CHEMCATCHEM, 2019, 11 (20) :4983-4997
[10]   Development of a direct polycondensation process for poly (L-lactic acid) [J].
Fukushima, T ;
Sumihiro, Y ;
Koyanagi, K ;
Hashimoto, N ;
Kimura, Y ;
Sakai, T .
INTERNATIONAL POLYMER PROCESSING, 2000, 15 (04) :380-385