A comprehensive review on metal based active sites and their interaction with O3 during heterogeneous catalytic ozonation process: Types, regulation and authentication

被引:72
作者
Chen, Weirui [1 ]
He, Hengxi [2 ]
Liang, Jiantao [2 ]
Wei, Xipeng [1 ]
Li, Xukai [2 ]
Wang, Jing [2 ]
Li, Laisheng [2 ]
机构
[1] Guangdong Univ Technol, Sch Environm Sci & Engn, Guangzhou 510006, Peoples R China
[2] South China Normal Univ, Guangdong Prov Engn Technol Res Ctr Drinking Water, Sch Environm, Guangdong Prov Key Lab Funct Mat Environm Protect, Guangzhou 510006, Peoples R China
基金
中国国家自然科学基金;
关键词
Ozone activation; Metal -based active sites; SluggishMe((n+m)+)/Men+ redox cycle; Regulation and Authentication of active sites; P-CHLOROBENZOIC ACID; ZERO-VALENT IRON; SURFACE HYDROXYL-GROUPS; AQUEOUS-SOLUTION; EFFICIENT DEGRADATION; OXALIC-ACID; PHOTOCATALYTIC OZONATION; CLOFIBRIC ACID; WASTE-WATER; DIMETHYL PHTHALATE;
D O I
10.1016/j.jhazmat.2022.130302
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Heterogeneous catalytic ozonation (HCO) was a promising water purification technology. Designing novel metal -based catalysts and exploring their structural-activity relationship continued to be a hot topic in HCO. Herein, we reviewed the recent development of metal-based catalysts (including monometallic and polymetallic catalysts) in HCO. Regulation of metal based active sites (surface hydroxyl groups, Lewis acid sites, metal redox cycle and surface defect) and their key roles in activating O-3 were explored. Advantage and disadvantage of conventional characterization techniques on monitoring metal active sites were claimed. In situ electrochemical character-ization and DFT simulation were recommended as supplement to reveal the metal active species. Though the ambiguous interfacial behaviors of O-3 at these active sites, the existence of interfacial electron migration was beyond doubt. The reported metal-based catalysts mainly served as electron donator for O-3, which resulted in the accumulation of oxidized metal and reduced their activity. Design of polymetallic catalysts could accelerate the interfacial electron migration, but they still faced with the dilemma of sluggish Me(n+m)+/Men+ redox cycle. Alternative strategies like coupling active metal species with mesoporous silicon materials, regulating surface hydrophobic/hydrophilic properties, polaring surface electron distribution, coupling HCO process with photo -catalysis and H2O2 were proposed for future research.
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页数:22
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