An investigation on the adsorption and removal performance of a carboxymethylcellulose-based 4-aminophenazone@MWCNT nanocomposite against crystal violet and brilliant green dyes

被引:18
作者
Althomali, Raed H. [1 ]
Alamry, Khalid A. [1 ]
Hussein, Mahmoud A. [1 ,2 ]
Guedes, R. M. [3 ]
机构
[1] King Abdulaziz Univ, Fac Sci, Dept Chem, Jeddah 21589, Saudi Arabia
[2] Assiut Univ, Fac Sci, Chem Dept, Assiut 71516, Egypt
[3] Fac Engn Uni Porto FEUP, Mech Engn Dept, DEMec, LAETA INEG, Rua Dr Roberto Frias s-n, P-4200465 Porto, Portugal
关键词
CARBON NANOTUBE MWCNT; PHOTOCATALYTIC DEGRADATION; WASTE-WATER; NANOPARTICLES; STARCH; BEADS; TIO2;
D O I
10.1039/d2ra07321h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The multistep chemical modification of carboxymethylcellulose (CMC) in the presence of 4-aminophenazone (A-PH) and multiwall carbon nanotubes (MWCNTs) has been successfully conducted. The environmental performance of this material has been thoroughly investigated. Crystal violet (CV) and brilliant green (BG) were eliminated by utilising a new hybrid nanocomposite material (A-PH-CMC/MWCNTs) from a simulated textile wastewater solution. Using SEM, EDX, XRD and FTIR spectroscopy methods, the detailed characterisation of A-PH-CMC/MWCNT nanocomposites was investigated. The results indicated that the adsorption capacity was dependent on six factors (e.g., contact duration, starting concentration, adsorbent mass, the effect of the solution pH, temperature and the effect of KNO3). In addition, thermodynamic and regeneration studies have been reported. According to the theories of pseudo-second-order kinetics, the removal process involves chemical adsorption. The experimental results were best suited by the Langmuir model, in which maximum adsorption capacities of 20.83 and 22.42 mg g(-1) were predicted for the BG and CV dyes, respectively. The research is a preliminary case study demonstrating the excellent potential of A-PH-CMC/MWCNT nanocomposites as a material for CV and BG dye removal.
引用
收藏
页码:4303 / 4313
页数:11
相关论文
共 50 条
[1]  
Abuilaiwi FA, 2010, ARAB J SCI ENG, V35, P37
[2]   Studies on adsorption of crystal violet dye from aqueous solution onto coniferous pinus bark powder (CPBP) [J].
Ahmad, Rais .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 171 (1-3) :767-773
[3]  
Al-Yousefi D. A., 2022, AIP Conf Proc., V2386, DOI DOI 10.1063/5.0067206
[4]   Modification of alginic acid for the removal of dyes from aqueous solutions by solid-phase extraction [J].
Althomali, Raed H. ;
Alamry, Khalid A. ;
Hussein, Mahmoud A. ;
Khan, Ajahar ;
Al-Juaid, Salih S. ;
Asiri, Abdullah M. .
INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY, 2022, 102 (16) :3673-3693
[5]   Synthesis of TiO2 nanoparticles and decorated multi-wall carbon nanotube (MWCNT) with anatase TiO2 nanoparticles and study of optical properties and structural characterization of TiO2/MWCNT nanocomposite [J].
Askari, Mohammad Bagher ;
Banizi, Zoha Tavakoli ;
Seifi, Majid ;
Dehaghi, Sedigheh Bagheri ;
Veisi, Payam .
OPTIK, 2017, 149 :447-454
[6]   Synthesis and modification of multi-walled carbon nano-tubes (MWCNTs) for water treatment applications [J].
Bahgat, M. ;
Farghali, A. A. ;
El Rouby, W. M. A. ;
Khedr, M. H. .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2011, 92 (02) :307-313
[7]   Adsorption of Carboxymethyl Cellulose onto Titania Particle Films Studied with in Situ IR Spectroscopic Analysis [J].
Botka, Bea ;
McQuillan, A. James ;
Krasowska, Marta ;
Beattie, David A. .
LANGMUIR, 2019, 35 (33) :10734-10743
[8]   Fluorine-Enhanced Catalytic Activity of Polyaniline-Supported Copper Nanoparticles in Buchwald-Hartwig Couplings of Pyrimidin-2-Amines [J].
Chen, Ying ;
Yu, Lei ;
Zhou, Hongwei .
JOURNAL OF PHYSICAL CHEMISTRY C, 2022, 126 (40) :17084-17092
[9]   Cholesterol and fat lowering with hydrophobic polysaccharide derivatives [J].
Copikova, Jana ;
Taubner, Tomas ;
Tuma, Jan ;
Synytsya, Andriy ;
Duskova, Dagmar ;
Marounek, Milan .
CARBOHYDRATE POLYMERS, 2015, 116 :207-214
[10]  
Cui Y., 2022, ENVIRON SCI POLLUT R, P1