Performance of Continuous Emission Monitoring Solutions under a Single-Blind Controlled Testing Protocol

被引:20
|
作者
Bell, Clay [1 ,2 ]
Ilonze, Chiemezie [3 ]
Duggan, Aidan [1 ]
Zimmerle, Daniel [1 ]
机构
[1] Colorado State Univ, Energy Inst, Ft Collins, CO 80524 USA
[2] BPX Energy, Denver, CO 80202 USA
[3] Colorado State Univ, Dept Mech Engn, Ft Collins, CO 80523 USA
关键词
Methane; emissions mitigation; detection limit; emissions quantification; source attribution; natural gas; GAS PRODUCTION SITES; METHANE EMISSIONS; PROCESS EQUIPMENT;
D O I
10.1021/acs.est.2c09235
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Continuous emission monitoring (CM) solutions promise to detect large fugitive methane emissions in natural gas infrastructure sooner than traditional leak surveys, and quantification by CM solutions has been proposed as the foundation of measurement-based inventories. This study performed single-blind testing at a controlled release facility (release from 0.4 to 6400 g CH4/h) replicating conditions that were challenging, but less complex than typical field conditions. Eleven solutions were tested, including point sensor networks and scanning/imaging solutions. Results indicated a 90% probability of detection (POD) of 3-30 kg CH4/h; 6 of 11 solutions achieved a POD < 6 kg CH4/h, although uncertainty was high. Four had true positive rates > 50%. False positive rates ranged from 0 to 79%. Six solutions estimated emission rates. For a release rate of 0.1-1 kg/h, the solutions' mean relative errors ranged from -44% to +586% with single estimates between -97% and +2077%, and 4 solutions' upper uncertainty exceeding +900%. Above 1 kg/h, mean relative error was -40% to +93%, with two solutions within +/- 20%, and single-estimate relative errors were from -82% to +448%. The large variability in performance between CM solutions, coupled with highly uncertain detection, detection limit, and quantification results, indicates that the performance of individual CM solutions should be well understood before relying on results for internal emissions mitigation programs or regulatory reporting.
引用
收藏
页码:5794 / 5805
页数:12
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