Characterization of a new sustainable supramolecular solvent and application to the determination of oxy-PAHs in meat, seafood and fish tissues

被引：10

作者：

Duenas-Mas, Maria Jesus ^{[1
]}

Ballesteros-Gomez, Ana ^{[1
]}

Rubio, Soledad ^{[1
]}

机构：

[1] Univ Cordoba, Inst Chem Energy & Environm, Dept Analyt Chem, Marie Curie Bldg Annex,Campus Rabanales, Cordoba 14071, Spain

来源：

FOOD CHEMISTRY | 2023年 / 405卷

关键词：

oxy-PAHs; Emerging contaminants; Supramolecular solvents; High resolution mass spectrometry; Food samples; Microextraction; 68179800); 6H-benzo[cd]pyren-6-one (PubChem; 18311); information; POLYCYCLIC AROMATIC-HYDROCARBONS; OXYGENATED-PAHS; LIQUID-CHROMATOGRAPHY; HEALTH-RISK; PARENT; EXTRACTION; AEROSOL; IMPACT; DUST; TIME;

D O I：

10.1016/j.foodchem.2022.134731

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

In this study we develop a green treatment method based on supramolecular solvents (SUPRASs) made up of reverse aggregates of short/medium chain length alcohols (C6-C10) in mixtures of water and a sustainable organic solvent (methyl-tetrahydrofuran). SUPRASs ingredients have low toxicity and can be obtained from renewable sources. The new SUPRASs were characterized and its suitability for determination of oxygenated polycyclic aromatic hydrocarbons (oxy-PAHs) in food was tested. Analysis was made by liquid chromatography coupled to high resolution mass spectrometry. The method provided quantification limits in the range 0.4-4 ng g-1 with low consumption of reagents (200uL of SUPRAS per sample) and it was based on simple agitation and centrifugation without concentration/evaporation steps. All target compounds (except 11-H-benzo[b]fluoren-11-one) were found in 7 out of 19 samples, mainly in fish and seafood samples, with levels in the range n.d. - 8 ng g-1.

引用

页数：9

共 39 条

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