Hydrangea-like MoS2/carbon dots anode for high-performance sodium storage

被引:21
作者
Wang, Yan [1 ,2 ,4 ]
Wang, Qing [1 ,2 ,3 ,4 ]
Liu, Wuxin [1 ,2 ,4 ]
Wei, Yuli [1 ,2 ,4 ]
Wang, Shasha [1 ,2 ,4 ]
Luo, Shaohua [1 ,2 ,3 ,4 ]
Zhang, Yahui [1 ,2 ,3 ,4 ]
Hou, Pengqing [3 ,4 ,5 ]
Yan, Shengxue [1 ,2 ,3 ,4 ]
Liu, Xin [1 ,2 ,3 ,4 ]
Guo, Jing [1 ,2 ,3 ,4 ]
机构
[1] Northeastern Univ, Sch Mat Sci & Engn, Shenyang 110819, Peoples R China
[2] Northeastern Univ, State Key Lab Rolling & Automat, Shenyang 110819, Peoples R China
[3] Northeastern Univ Qinhuangdao, Sch Resources & Mat, Qinhuangdao 066004, Peoples R China
[4] Hebei Key Lab Dielect & Electrolyte Funct Mat, Qinhuangdao 066004, Peoples R China
[5] Shenyang Univ Technol, Sch Mat Sci & Engn, Shenyang 110870, Peoples R China
关键词
Carbon dots; MoS; 2; Anodes; Sodium-ion battery; MOS2; LITHIUM;
D O I
10.1016/j.jcis.2023.11.030
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Owing to their quantum size, edge effects, and abundant surface functional groups, carbon dots (CDs) have attracted significant attention. In this study, chitin-derived carbon dots (CT-CDs) were prepared and used to synthesize MoS2/CT-CDs. The abundant functional groups on the surface of the CT-CDs facilitated the orderly arrangement of MoS2 nanosheets, resulting in a hydrangea-like structure. When employed as the anode in a sodium-ion battery, MoS2/CT-CDs exhibited an excellent initial charging capacity of 492.6 mAh & sdot;g- 1 at 0.1 A & sdot;g- 1 with an initial Coulomb efficiency of 74.4%. Even after 100 cycles, the reversible capacity remained at 338.9 mAh & sdot;g- 1. Furthermore, the reversible capacity of MoS2/CT-CDs remained at 219.9 mAh & sdot;g- 1 after 260 cycles when subjected to 1 A & sdot;g- 1. The hydrangea-like structure of MoS2/CT-CDs, with expanded layer spacing, enhances ion/electron transport while providing additional active sites for sodium-ion storage, resulting in exceptional cycling and rate performances.
引用
收藏
页码:407 / 416
页数:10
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