Novel microwave dielectric ceramics based on CaO-MoO3-La2O3 pseudo-ternary phase diagram and the design of patch antenna

被引:18
作者
Bao, Jian [1 ,2 ]
Du, Wei [1 ]
Wu, Haitao [1 ]
Yue, Zhenxing [3 ]
机构
[1] Yantai Univ, Sch Environm & Mat Engn, Yantai 264005, Shandong, Peoples R China
[2] Univ Jinan, Sch Mat Sci & Engn, Jinan, Peoples R China
[3] Tsinghua Univ, Sch Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China
基金
中国国家自然科学基金;
关键词
5G patch antenna; CaO-MoO3-La2O3; LTCC; THz time-domain spectrum; CHEMICAL-BOND CHARACTERISTICS; CAO-B2O3-SIO2; GLASS; CRYSTAL-STRUCTURE; MICROSTRUCTURE; SPECTROSCOPY; FERGUSONITE; SPECTRUM; SR; CA; CU;
D O I
10.1111/jace.19524
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In this study, two novel microwave dielectric ceramics were designed and synthesized using the solid-state reaction method based on the CaO-MoO3-La2O3 pseudo-ternary phase diagram. The X-ray diffraction (XRD) patterns and Rietveld refinement results indicate that pure phase microwave dielectric ceramics (CaLa2(MoO4)(4) and Ca3MoO6) can be produced with CaO, MoO3, La2O3 ratios of 1, 1, 4, and 3, 1, 0, respectively. CaLa2(MoO4)(4) shows the potential value for application in Low Temperature Co-fired Ceramic technology. In addition, the Phillips-van Vechten-Levine theory, infrared reflectance spectrum, and THz time-domain spectrum are used further to study the structure-property relationship of the two ceramics. Finally, a 5G patch antenna used in Sub-6 GHz communication technology was successfully designed and manufactured. The study of the relationship between chemical bonds and dielectric properties of the two ceramics, along with the development of the patch antenna, establishes a foundation for scientific research and practical applications in related ceramic systems.
引用
收藏
页码:704 / 718
页数:15
相关论文
共 35 条
  • [1] Crystal structure, chemical bond characteristics, infrared reflection spectrum, and microwave dielectric properties of Nd2(Zr1-xTix)3(MoO4)9 ceramics
    Bao, Jian
    Zhang, Yuping
    Kimura, Hideo
    Wu, Haitao
    Yue, Zhenxing
    [J]. JOURNAL OF ADVANCED CERAMICS, 2023, 12 (01): : 82 - 92
  • [2] Crystal structure, chemical bond characteristics, and microwave dielectric properties of novel Sr2CaMoO6 ceramic at different sintering temperatures
    Bao Jian
    Chen Yueguang
    Zhou Yuanyuan
    Guo Weijia
    Zhang Yuping
    Du Jialun
    Wu Haitao
    Yue Zhenxing
    [J]. CERAMICS INTERNATIONAL, 2023, 49 (01) : 335 - 344
  • [3] Crystal structure, Raman spectrum, bond characteristics, and terahertz time-domain spectrum of novel Na5Tm(MoO4)4 microwave dielectric ceramic with ultra-low sintering temperature and high quality factor
    Bao, Jian
    Li, Hu
    Xu, Xiaoyu
    Guo, Weijia
    Chen, Yueguang
    Zhang, Yuping
    Du, Jialun
    Wu, Haitao
    Duan, Guangbin
    Yue, Zhenxing
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2023, 939
  • [4] Sintering characteristics, crystal structure and dielectric properties of cobalt-tungsten doped molybdate-based ceramics at microwave frequency
    Bao, Jian
    Zhang, Yuping
    Wu, Haitao
    Zhou, Yuanyuan
    Yue, Zhenxing
    [J]. JOURNAL OF MATERIOMICS, 2022, 8 (05) : 949 - 957
  • [5] BATSANOV SS, 1982, USP KHIM+, V51, P1201
  • [6] Phase composition, microstructure and microwave dielectric properties of rock salt structured Li2ZrO3-MgO ceramics
    Bi, J. X.
    Xing, C. F.
    Yang, C. H.
    Wu, H. T.
    [J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2018, 38 (11) : 3840 - 3846
  • [7] Parallel preparation and properties investigation on Li2O-Nb2O5-TiO2 microwave dielectric ceramics
    Chang, Jian
    Liu, Zhifu
    Ma, Mingsheng
    Li, Yongxiang
    [J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2017, 37 (13) : 3951 - 3957
  • [8] Entropy regulation in LaNbO4-based fergusonite to implement high-temperature phase transition and promising dielectric properties
    Chen, Deqin
    Yan, Na
    Cao, Xuefeng
    Li, Fengrong
    Liu, Laijun
    Shen, Qinghua
    Zhou, Huanfu
    Li, Chunchun
    [J]. JOURNAL OF ADVANCED CERAMICS, 2023, 12 (05): : 1067 - 1080
  • [9] Phase equilibria and microwave dielectric properties in the ternary La2O3-TiO2-Nb2O5 system
    Golobic, A.
    Meden, A.
    Spreitzer, M.
    Skapin, S. D.
    [J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2021, 41 (14) : 7035 - 7043
  • [10] Lattice dynamics and terahertz response of microwave dielectrics: A case study of Al-doped Ca0.6Sm0.27TiO3 ceramics
    Guo, Weijia
    Ma, Zhiyu
    Chen, Yugu
    Lu, Yutian
    Yue, Zhenxing
    [J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2022, 42 (12) : 4953 - 4961