Copper-catalyzed 1,2-borocarbonylation of unactivated alkenes

被引：4

作者：

Zhao, Fengqian ^{[1
]}

Xu, Jian-Xing ^{[2
]}

Wu, Fu-Peng ^{[1
]}

Wu, Xiao-Feng ^{[1
,2
]}

机构：

[1] Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany

[2] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China

来源：

JOURNAL OF CATALYSIS | 2023年 / 417卷

关键词：

Copper; Carbonylation; Alkene; Organoboron; Cross; -Coupling; BOROACYLATION;

D O I：

10.1016/j.jcat.2022.12.027

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Copper-catalyzed borocarbonylation of terminal alkenes usually gives terminal boron substituted /3-boryl carbonyl compounds. In this communication, a copper-catalyzed selectivity-reversed borocarbonylation has been described. In the presence of CuOAc/BuPAd2 catalytic system, a series of unactivated terminal alkenes were transformed into /3-boryl ketones in moderate yields, with sterically hindered alkyl bro-mides as the electrophiles.CO 2022 Elsevier Inc. All rights reserved.

引用

页码：379 / 381

页数：3

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