In situ growth of Prussian blue analogue-derived Fe-doped NiS on Ni(OH)2 for efficient hydrogen evolution reaction

被引：10
|
作者：
Ding, Xinyao [1 ]
Zhang, Mingyi [1 ]
Chang, Xin [1 ]
Zhou, Xuejiao [1 ]
机构：
[1] Harbin Normal Univ, Sch Phys & Elect Engn, Key Lab Photon & Elect Bandgap Mat, Minist Educ, Harbin 150025, Peoples R China
来源：
DALTON TRANSACTIONS | 2023年 / 52卷 / 06期
基金：
中国国家自然科学基金;
关键词：
HIGHLY EFFICIENT; ELECTROCATALYSTS; MODULATION;
D O I：
10.1039/d2dt03332a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The energy industry is placing more and more emphasis on the need for effective and affordable electrocatalysts for hydrogen evolution reactions (HER). In this work, an iron-doped NiS/Ni(OH)(2)/CC composite material was synthesized by simple hydrothermal sulfurization processes of bimetallic Prussian blue analogue (PBAs) precursors grown in situ on three-dimensional (3D) Ni(OH)(2) nanosheets. The overpotential can be 103 mV to attain current densities of 10 mA cm(-2). The excellent catalytic activity of Fe-NiS/Ni(OH)(2)/CC is because of the unique 3D structure and the uniform doping of iron caused by the in situ growth of PBA, as well as the high conductivity of the self-supported electrode carbon cloth.
引用
收藏
页码：1680 / 1686
页数：7
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