Translating aqueous CO2 hydrogenation activity to electrocatalytic reduction with a homogeneous cobalt catalyst

被引：4
|
作者：
Wang, Xinran S. [1 ]
Yang, Jenny Y. [1 ]
机构：
[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA
来源：
CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 03期
关键词：
CARBON-DIOXIDE; THERMODYNAMIC HYDRICITY; FORMATE; SOLVENT; OXIDATION;
D O I：
10.1039/d2cc05473f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A molecular cobalt CO2 hydrogenation catalyst was explored for electrocatalytic CO2 reduction under aqueous conditions. The resulting pH-dependent selectivity between H-2 and HCO2- is rationalized with thermodynamic analysis and stoichiometric experiments.
引用
收藏
页码：338 / 341
页数：4
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