Reversible spin-state switching triggered by humidity capture-release cycle under ambient condition

被引:5
作者
Dong, Hui [1 ]
Jin, Xue-Ting [1 ]
Zhao, Jie [1 ]
Xue, Cheng [1 ]
Zhang, Shuxin [1 ]
Liu, Min [1 ]
Luo, Yang-Hui [1 ]
机构
[1] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Peoples R China
关键词
THIN-FILMS; COORDINATION POLYMERS; CROSSOVER MATERIALS; TRANSITION; BEHAVIOR; COMPLEX; GELS;
D O I
10.1016/j.mtchem.2023.101805
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Combining the fascinating advantages of atmospheric humidity with the phenomenon of spin-state switching (SSS) materials represents an attractive way of triggering the reversible SSS under ambient conditions. In this work, the occurrence of the reversible SSS triggered by the humidity capture/release cycle without the addition of external energy was achieved by mixing composite gels with the two-dimensional ferrous complex. A linear relationship between humidity absorption amounts and the color of the composite gel was established, which facilitates the manufacture of a novel SSS device. This work has provided a new design strategy to motivate SSS performance and may open the way for practical applications of SSS.
引用
收藏
页数:6
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共 43 条
[1]   Tunable mechanical properties of [Fe(pyrazine){Au(CN)2}2]-PVDF composite films with spin transitions [J].
Bibik, Yurii S. ;
Angulo-Cervera, Jose E. ;
Lampeka, Rostyslav D. ;
Gural'skiy, Il'ya A. .
POLYMER, 2022, 238
[2]   A Two-Coordinate Iron(II) Imido Complex with NHC Ligation: Synthesis, Characterization, and Its Diversified Reactivity of Nitrene Transfer and C-H Bond Activation [J].
Cheng, Jun ;
Liu, Jian ;
Leng, Xuebing ;
Lohmiller, Thomas ;
Schnegg, Alexander ;
Bill, Eckhard ;
Ye, Shengfa ;
Deng, Liang .
INORGANIC CHEMISTRY, 2019, 58 (11) :7634-7644
[3]   Spin state behavior of iron(II)/dipyrazolylpyridine complexes. New insights from crystallographic and solution measurements [J].
Cook, Laurence J. Kershaw ;
Mohammed, Rufeida ;
Sherborne, Grant ;
Roberts, Thomas D. ;
Alvarez, Santiago ;
Halcrow, Malcolm A. .
COORDINATION CHEMISTRY REVIEWS, 2015, 289 :2-12
[4]   Molecular magnetism: from chemical design to spin control in molecules, materials and devices [J].
Coronado, Eugenio .
NATURE REVIEWS MATERIALS, 2020, 5 (02) :87-104
[5]   Structure-property relationships and the mechanisms of multistep transitions in spin crossover materials and frameworks [J].
Cruddas, Jace ;
Powell, Ben J. .
INORGANIC CHEMISTRY FRONTIERS, 2020, 7 (22) :4424-4437
[6]   Colored contact lens with all-weather humidity-triggered discoloration [J].
Dong, Hui ;
Jin, Xue-Ting ;
Zhang, Shu-Xin ;
Xue, Cheng ;
Liu, Min ;
Luo, Yang-Hui .
DYES AND PIGMENTS, 2023, 218
[7]   Spin crossover of a dinuclear Fe(II) complex in the trans-isomeric structure [J].
Dong, Ya-Nan ;
Xue, Jin-Peng ;
Yu, Meng ;
Tao, Jun .
INORGANIC CHEMISTRY COMMUNICATIONS, 2022, 140
[8]   Structure of a spin-crossover Fe(II)-1,2,4-triazole polymer complex gel in toluene. Small angle neutron scattering and viscoelastic studies [J].
Echeverria, Coro ;
Rubio, Miguel ;
Mitchell, Geoffrey R. ;
Lopez, Daniel .
EUROPEAN POLYMER JOURNAL, 2014, 53 :238-245
[9]   Spin crossover polymer composites, polymers and related soft materials [J].
Enriquez-Cabrera, Alejandro ;
Rapakousiou, Amalia ;
Bello, Mario Piedrahita ;
Molnar, Gabor ;
Salmon, Lionel ;
Bousseksou, Azzedine .
COORDINATION CHEMISTRY REVIEWS, 2020, 419
[10]   Spin-crossover physical gels: A quick thermoreversible response assisted by dynamic self-organization [J].
Fujigaya, Tsuyohiko ;
Jiang, Dong-Lin ;
Aida, Takuzo .
CHEMISTRY-AN ASIAN JOURNAL, 2007, 2 (01) :106-113