Desorption of cadmium from Fe≡Cd and recycle of Fe0: Experimental and mechanism study

Zero valent iron (Fe-0) has been proven to be a highly efficient adsorption material for cadmium in wastewater. However, how to deal with Fe-0 after cadmium adsorption, restricts its industrialization. In this paper, we attempted to desorb cadmium from the post-adsorption material (Fe equivalent to Cd) through ammoniacal leaching and recycle the Fe-0. Desorption experiments, Infrared and SEM-EDS results showed leaching with (NH4)(2)SO4 and NH3 center dot H2O can effectively desorb cadmium from Fe equivalent to Cd. Based on Ultraviolet spectrum, solution chemistry and quantum chemical analysis, cadmium on Fe equivalent to Cd can combine with free ammonia and form Cd-NH3 complexes. Then the complexes are transferred into the leached solution, achieving the desorption of cadmium. Subsequently, cadmium in leached solution was precipitated into Cd(OH)(2), a high-grade cadmium product. Finally, the cadmium adsorption capability of regenerated Fe-0 was roughly investigated, and the results showed that it has a better capability for cadmium adsorption than initial Fe-0, which further guaranteed the recycle of Fe-0.