Hybrid Catalysts for Enantioselective Photo-Phosphoric Acid Catalysis

被引：11
|
作者：
Rolka, Alessa B. [1 ,2 ]
Archipowa, Nataliya [3 ]
Kutta, Roger J. [4 ]
Koenig, Burkhard [1 ]
Toste, F. Dean [2 ]
机构：
[1] Univ Regensburg, Inst Organ Chem, Fac Chem & Pharm, D-93040 Regensburg, Germany
[2] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[3] Univ Regensburg, Inst Biophys & Phys Biochem, Fac Biol & Preclin Med, D-93040 Regensburg, Germany
[4] Univ Regensburg, Inst Theoret & Phys Chem, Fac Chem & Pharm, D-93040 Regensburg, Germany
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 88卷 / 10期
基金：
美国国家卫生研究院;
关键词：
2+2 PHOTOCYCLOADDITION REACTIONS; BRONSTED ACID; THIOXANTHONE; ALKYLATION; POTENTIALS; SENSITIZER; ALDEHYDES; RADICALS; IMINIUM; SINGLET;
D O I：
10.1021/acs.joc.3c00191
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The syntheses of two novel, organic, and chiral photocatalysts are presented. By combining donor-acceptor cyanoarene-based photocatalysts with a chiral phosphoric acid, bifunctional catalysts have been designed. In preliminary proof-of concept reactions, their use in both enantioselective energy transfer and photoredox catalysis is demonstrated.
引用
收藏
页码：6509 / 6522
页数：14
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