State-of-the-art luminescent materials based on wood veneer with superior strength, transparency, and water resistance

被引:14
|
作者
Wang, Ming [1 ,2 ]
Liu, Hongchen [1 ,4 ]
Feng, Xiao [1 ]
Wang, Xijun [1 ]
Shen, Kaiyuan [1 ]
Qi, Haisong [1 ]
Rojas, Orlando J. [2 ,3 ,5 ]
机构
[1] South China Univ Technol, State Key Lab Pulp & Paper Engn, Guangzhou 510641, Peoples R China
[2] Univ British Columbia, Bioproducts Inst, Dept Chem & Biol Engn, Dept Chem, 2360East Mall, Vancouver, BC V6T IZ3, Canada
[3] Univ British Columbia, Dept Wood Sci, 2360East Mall, Vancouver, BC V6T IZ3, Canada
[4] Zhongyuan Univ Technol, Coll Text, Zhengzhou 450007, Peoples R China
[5] Aalto Univ, Sch Chem Engn, Dept Bioproducts & Biosyst, POB 16300, FIN-00076 Espoo, Finland
基金
加拿大创新基金会; 欧洲研究理事会;
关键词
Transparent wood; Aggregation-induced emission; Wood nanotechnology; UV-blocking; Wood-based fluorescent films; AGGREGATION-INDUCED EMISSION; CARBON DOTS; FILM;
D O I
10.1016/j.cej.2022.140225
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Current energy and luminescent materials utilize polymers to encapsulate fluorescent carbon nanodots and dyes but they usually lack stability and biodegradability. Here, we introduce an alternative wood nanotechnology to produce luminescent films (veneer) with UV resistance and tailorable surface energy. First, fluorescent and transparent wood (FTW) is shown as a support of aggregation-induced fluorescent emission (AIE) by in-situ Hantzsch reaction of acetoacetate delignified wood (AA-DW). Highly aligned cellulose nanofibers present in AA-DW facilitate FTW densification, ensuing exceptional mechanical performance (tensile strength and Young's modulus of up to 422 MPa and 45 GPa, respectively). Simultaneously, the conjugated structures display high transparency (83 %), haze (80 %) and optical anisotropy. The new luminescent system is demonstrated to be biodegradable and effective in optical (fluorescent) windows as well as encrypted films.
引用
收藏
页数:8
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