Effect of Permittivity on the Ionic Boundary Layer upon Protonation of Lithium Niobate

被引:0
作者
Demin, Vitaly A. [1 ]
Petukhov, Maxim I. [1 ]
Ponomarev, Roman S. [1 ]
Kuneva, Mariana K. [2 ]
机构
[1] Perm State Univ, Perm, Russia
[2] BAS, Inst Solid State Phys, Sofia, Bulgaria
来源
JOURNAL OF SIBERIAN FEDERAL UNIVERSITY-MATHEMATICS & PHYSICS | 2023年 / 16卷 / 05期
关键词
proton exchange; boundary layer; permittivity; numerical simulation; WAVE-GUIDES; X-CUT; EXCHANGE; INDEX;
D O I
暂无
中图分类号
O1 [数学];
学科分类号
0701 ; 070101 ;
摘要
The paper presents the results of a numerical study of the behavior of proton exchange reaction products after they enter benzoic acid, which interacts with a lithium niobate crystal. The theoretical model based on the continuous media approximation considers the convective transfer and diffusion of positively charged lithium ions and negatively charged benzoate ions. Additionally, the possibility of their recombination with the subsequent formation of lithium benzoate molecules is taken into account. The results obtained correspond to stationary, uniform along the interface, profiles of the ion concentration and electric potential. In the process of establishment, benzoate ions form an ionic boundary layer. An analysis is made of the influence of the dielectric constant of the carrier liquid on its characteristics.
引用
收藏
页码:611 / 619
页数:9
相关论文
共 24 条
[1]   INDEPENDENT CONTROL OF INDEX AND PROFILES IN PROTON-EXCHANGED LITHIUM-NIOBATE GUIDES [J].
DEMICHELI, M ;
BOTINEAU, J ;
NEVEU, S ;
SIBILLOT, P ;
OSTROWSKY, DB ;
PAPUCHON, M .
OPTICS LETTERS, 1983, 8 (02) :114-115
[2]   An Ionic Boundary Layer near the Lithium Niobate Surface in the Proton Exchange Process [J].
Demin, V. A. ;
Petukhov, M. I. ;
Ponomarev, R. S. .
SURFACE ENGINEERING AND APPLIED ELECTROCHEMISTRY, 2023, 59 (03) :321-328
[3]  
Demin V. A., 2021, B PERM U PHYS, V1, P49, DOI DOI 10.17072/1994-3598-2021-1-49-58
[4]  
FRANCK EU, 1978, FARADAY DISCUSS, V66, P191, DOI 10.1039/dc9786600191
[5]  
Gershuni G. Z., 1989, Convective Stability of Incompressible Fluids
[6]   CHARACTERIZATION OF PROTON-EXCHANGE AND ANNEALED LINBO3 WAVE-GUIDES WITH PYROPHOSPHORIC ACID [J].
GOTO, N ;
YIP, GL .
APPLIED OPTICS, 1989, 28 (01) :60-65
[7]   PROTON-EXCHANGE FOR HIGH-INDEX WAVEGUIDES IN LINBO3 [J].
JACKEL, JL ;
RICE, CE ;
VESELKA, JJ .
APPLIED PHYSICS LETTERS, 1982, 41 (07) :607-608
[8]  
JACKEL JL, 1991, P SOC PHOTO-OPT INS, V1583, P54, DOI 10.1117/12.50875
[9]   The dipole moment of alcohols in the liquid phase and in solution [J].
Jorge, Miguel ;
Gomes, Jose R. B. ;
Barrera, Maria Cecilia .
JOURNAL OF MOLECULAR LIQUIDS, 2022, 356
[10]  
Kichigin V. I., 2012, 2012 IEEE 13th International Conference and Seminar of Young Specialists on Micro/Nanotechnologies and Electron Devices (EDM 2012), P238, DOI 10.1109/EDM.2012.6310225