C@SnS2 core-shell 0D/2D nanocomposite with excellent electrochemical performance as lithium-ion battery anode

被引:3
作者
Jin, Changqing [1 ]
Wei, Yongxing [1 ]
Nan, Ruihua [1 ]
Jian, Zengyun [1 ]
Ding, Qingping [2 ,3 ]
机构
[1] Xian Technol Univ, Sch Mat & Chem Engn, Shaanxi Key Lab Optoelect Funct Mat & Devices, Xian 710021, Peoples R China
[2] Iowa State Univ, US DOE, Ames Natl Lab, Ames, IA 50011 USA
[3] Iowa State Univ, Dept Phys & Astron, Ames, IA 50011 USA
基金
中国国家自然科学基金;
关键词
Lithium-ion battery; Anode material; SnS2; Heterojunction; Carbon; HIGH REVERSIBLE CAPACITY; SNS2; NANOSHEETS; SNS2/GRAPHENE HYBRID; GRAPHENE; MICROSPHERES; COMPOSITES;
D O I
10.1016/j.electacta.2023.143747
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
C@SnS2 core -shell 0D/2D nanocomposite was successfully prepared by a one-step hydrothermal method. The SnS2 nanosheets were heterogeneously nucleated and grown on the surface of carbon spheres. As an anode for lithium -ion batteries, the electrochemical performance of the C@SnS2 composite outperforms that of SnS2 nanoflowers. After 100 cycles, the reversible discharge specific capacity reaches an impressive value of 802 mAh g-1 at a current density of 100 mA g-1. Even after 600 cycles, the discharge specific capacity remains a value of 442 mAh g-1, under a high current density of 1 A g-1. This remarkable lithium -ion storage performance can be attributed to the unique core -shell nanostructure and the synergy between SnS2 nanosheets and carbon spheres. This study advances our understanding of the vital role of carbon in fabricating nano-heterojunction or composite electrodes and provides a feasible route to significantly improve the electrochemical properties of SnS2 and other metal sulfides.
引用
收藏
页数:9
相关论文
共 50 条
[41]   Electrostatic Self-assembly of 0D–2D SnO2 Quantum Dots/Ti3C2Tx MXene Hybrids as Anode for Lithium-Ion Batteries [J].
Huan Liu ;
Xin Zhang ;
Yifan Zhu ;
Bin Cao ;
Qizhen Zhu ;
Peng Zhang ;
Bin Xu ;
Feng Wu ;
Renjie Chen .
Nano-Micro Letters, 2019, 11
[42]   One-pot hydrothermal synthesis of core-shell structured MnCO3@C as anode material for lithium-ion batteries with superior electrochemical performance [J].
Feng, Xiaoyu ;
Shen, Qiang ;
Shi, Yuanchang ;
Zhang, Jianxin .
ELECTROCHIMICA ACTA, 2016, 220 :391-397
[43]   Interface coupling 2D/2D SnSe2/graphene heterostructure as long-cycle anode for all-climate lithium-ion battery [J].
Chen, Hongwen ;
Liu, Rumin ;
Wu, Yang ;
Cao, Junhui ;
Chen, Jian ;
Hou, Yang ;
Guo, Yichuan ;
Khatoon, Rabia ;
Chen, Lingxiang ;
Zhang, Qinghua ;
He, Qinggang ;
Lu, Jianguo .
CHEMICAL ENGINEERING JOURNAL, 2021, 407
[44]   FexP/C core-shell nanocubes with large inner void space for advanced lithium-ion battery anode [J].
Zhang, Min ;
Wang, Huijun ;
Li, Qin ;
Feng, Jing ;
Chai, Yaqin ;
Yuan, Ruo ;
Yang, Xia .
APPLIED SURFACE SCIENCE, 2018, 453 :56-62
[45]   Nanostructured C@CuS Core-Shell Framework with High Lithium-Ion Storage Performance [J].
Jin, Changqing ;
Peng, Zaidong ;
Wei, Yongxing ;
Nan, Ruihua ;
Yang, Zhong ;
Jian, Zengyun ;
Ding, Qingping .
JOURNAL OF COMPOSITES SCIENCE, 2024, 8 (09)
[46]   The core-shell mesoporous titanium dioxide with in-situ nitrogen doped carbon as the anode for high performance lithium-ion battery [J].
Ji, Weiwei ;
Mei, Yeming ;
Yang, Ming ;
Liu, Hongli ;
Wang, Shirong ;
Shan, Zhongqiang ;
Ding, Fei ;
Liu, Xingjiang ;
Gao, Xueping ;
Li, Xianggao .
JOURNAL OF ALLOYS AND COMPOUNDS, 2019, 806 :946-952
[47]   100 K cycles: Core-shell H-FeS@C based lithium-ion battery anode [J].
Chen, Suhua ;
Fan, Ling ;
Xu, Lingling ;
Liu, Qian ;
Qin, Yong ;
Lu, Bingan .
ENERGY STORAGE MATERIALS, 2017, 8 :20-27
[48]   The double synergies of core-shell MnFe2O4@TiO2 mesoporous spheres for enhancing electrochemical performance of anode material as lithium-ion batteries [J].
Lu, Wangshu ;
Wang, Junkai ;
Zhao, Lijuan ;
Hu, Chunhua ;
Zhang, Xu ;
Duan, Lianfeng .
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, 2019, 242 :17-22
[49]   Preparation and characterization of core-shell structure Fe3O4/C nanoparticles with unique stability and high electrochemical performance for lithium-ion battery anode material [J].
Huang, Yudai ;
Dong, Zhifang ;
Jia, Dianzeng ;
Guo, Zaiping ;
Cho, Won Il .
ELECTROCHIMICA ACTA, 2011, 56 (25) :9233-9239
[50]   Comparative study of electrochemical properties of SnS and SnS2 as anode materials in lithium-ion batteries [J].
Glibo, Albina ;
Eshraghi, Nicolas ;
Surace, Yuri ;
Mautner, Andreas ;
Flandorfer, Hans ;
Cupid, Damian M. .
ELECTROCHIMICA ACTA, 2023, 441