Optical properties and corrosion resistance of Ti2AlC, Ti3AlC2, and Cr2AlC as candidates for concentrated solar power receivers

被引:14
作者
Azina, Clio [1 ]
Badie, Sylvain [2 ]
Litnovsky, Andrey [3 ]
Silvestroni, Laura [4 ]
Sani, Elisa [5 ]
Gonzalez-Julian, Jesus [2 ,6 ]
机构
[1] Rhein Westfal TH Aachen, Mat Chem, D-52074 Aachen, Germany
[2] Forsch Zentrum Julich, Inst Energy & Climate Research Mat Synth & Proc I, D-52425 Julich, Germany
[3] Forsch Zentrum Julich, Inst Energy & Climate Res Plasma Phys IEK 4, D-52425 Julich, Germany
[4] CNR, ISSMC Inst Sci Technol & Sustainabil Ceram, I-48018 Faenza, Italy
[5] CNR INO Natl Inst Opt, I-50125 Florence, Italy
[6] Rhein Westfal TH Aachen, Inst Mineral Engn, Chair Ceram, D-52074 Aachen, Germany
关键词
MAX phases; Concentrated solar power; Corrosion; Optical properties; HIGH-TEMPERATURE OXIDATION; PHASE-BASED CERAMICS; MAX PHASE; HOT CORROSION; ABSORBERS; CARBIDE; HAFNIUM; SUITABILITY; ZIRCONIUM;
D O I
10.1016/j.solmat.2023.112433
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
New generation concentrated solar power (CSP) plants require new solar receiver materials with selective optical properties and excellent corrosion resistance against molten salts. MAX phases are promising materials for CSP applications due to their optical properties and resistance to thermal shocks. Herein, we report a solar absorptance & GE;0.5 and a thermal emittance of 0.17-0.31 between 600 and 1500 K for Cr2AlC, Ti2AlC, and Ti3AlC2. These compositions were also exposed to solar salt corrosion at 600 degrees C for up to 4 weeks. Cr2AlC exhibited superior corrosion resistance due to the formation of a protective nanometric layer.
引用
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页数:6
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