Optimized synthesis of Na2/3Ni1/3Mn2/3O2 as cathode for sodium-ion batteries by rapid microwave calcination

被引：14
作者：
Bomio, M. R. D. [1 ]
Lavela, P. [2 ]
Santiago, A. A. G. [1 ]
Motta, F. V. [1 ]
Tirado, J. L. [2 ]
机构：
[1] Fed Univ Rio Grande do Norte UFRN, LSQM Lab Chem Synth Mat, Dept Mat Engn, POB 1524, Natal, RN, Brazil
[2] Univ Cordoba, Inst Univ Quim Fina & Nanoquim, Dept Quim Inorgan & Ingn Quim, Edificio Marie Curie,Campus Rabanales, Cordoba 14071, Spain
来源：
CERAMICS INTERNATIONAL | 2023年 / 49卷 / 08期
基金：
巴西圣保罗研究基金会;
关键词：
Sodium-ion batteries; Cathode; Layered oxides; Microwave calcination; P2-TYPE NA2/3NI1/3MN2/3O2; ENERGY-STORAGE; PERFORMANCE; TEMPLATE; VOLTAGE; P2;
D O I：
10.1016/j.ceramint.2022.12.105
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Microwave calcination is proposed as an alternative route to conventional heating to prepare layered P2-Na2/ 3Ni1/3Mn2/3O2 as a positive electrode for sodium-ion batteries. The sample obtained by the fastest conditions, with a heating ramp of 20 degrees C min-1 for only 2 h, showed well-crystallized rounded particles. Cyclic voltammetry and impedance spectroscopy evidenced a low internal cell resistance, and high diffusion coefficients, which justify its capability to sustain the highest capacity at 1 C and retain the discharge capacity for at least two hundred cycles.
引用
收藏
页码：12452 / 12461
页数：10
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