Synthesis and Application of Mesoporous Materials: Process Status, Technical Problems, and Development Prospects: A Mini-Review

被引:29
作者
Li, Zhuo [1 ]
Liu, Liying [1 ]
Wang, Zhe [1 ]
Gao, Peng [1 ]
Li, Gang Kevin [2 ]
机构
[1] Northeastern Univ, State Environm Protect Key Lab Ecoind, Shenyang 110819, Peoples R China
[2] Univ Melbourne, Dept Chem Engn, Parkville, Vic 3010, Australia
基金
中国国家自然科学基金;
关键词
HYDROTHERMAL SYNTHESIS; CATALYTIC CRACKING; DIBLOCK COPOLYMER; ANODE MATERIALS; ENERGY-STORAGE; SILICA; LITHIUM; CARBON; PERFORMANCE; FRAMEWORKS;
D O I
10.1021/acs.energyfuels.2c03882
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The world today is witnessing a new technological revolution, particularly in the area of new materials. Different types of materials often have different characteristics and uses. Mesoporous materials have a large specific surface area, easily modifiable inner and outer surfaces, tunable pore size and pore channels, and good biocompatibility and thermodynamic stability, thus emerging as a new candidate material in the chemical research community. The presence of mesopores facilitates the rapid diffusion of macromolecules, reduces resistance to mass transfer, and provides different properties depending on the pore size, making mesoporous materials a potential candidate for a wide range of applications. This paper reviews the recent methods used to synthesize mesoporous materials, including hydrothermal synthesis, microwave synthesis, the sol-gel method, the phase conversion method, and the templating method. The soft templating method is introduced in detail, including bulk self-assembly, solvent evaporation-induced self-assembly, solution-based nanoprecipitation, interfacial self-assembly in a solution, and emulsion template self-assembly. The current status of the processes related to mesoporous materials in the fields of biomedicine, environmental and energy, electrochemical energy storage, and gas separation is elaborated. Finally, the technical issues and future directions in the synthesis and application of mesoporous materials are briefly discussed.
引用
收藏
页码:3413 / 3427
页数:15
相关论文
共 115 条
[91]   New Insight into the Synthesis of Large-Pore Ordered Mesoporous Materials [J].
Wei, Jing ;
Sun, Zhenkun ;
Luo, Wei ;
Li, Yuhui ;
Elzatahry, Ahmed A. ;
Al-Enizi, Abdullah M. ;
Deng, Yonghui ;
Zhao, Dongyuan .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (05) :1706-1713
[92]   Design and Preparation of Porous Polymers [J].
Wu, Dingcai ;
Xu, Fei ;
Sun, Bin ;
Fu, Ruowen ;
He, Hongkun ;
Matyjaszewski, Krzysztof .
CHEMICAL REVIEWS, 2012, 112 (07) :3959-4015
[93]   Direct Synthesis of Cubic Benzene-Bridged Mesoporous Organosilica Functionalized with Mercaptopropyl Groups as an Effective Adsorbent for Mercury and Silver Ions [J].
Wu, Hao-Yiang ;
Chen, Ching-Ting ;
Hung, I-Ming ;
Liao, Chia-Hsiu ;
Vetrivel, Shanmugam ;
Kao, Hsien-Ming .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (15) :7021-7029
[94]   One-pot generation of mesoporous carbon supported nanocrystalline calcium oxides capable of efficient CO2 capture over a wide range of temperatures [J].
Wu, Zhangxiong ;
Hao, Na ;
Xiao, Gongkui ;
Liu, Liying ;
Webley, Paul ;
Zhao, Dongyuan .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (07) :2495-2503
[95]   Comprehensive Study of Pore Evolution, Mesostructural Stability, and Simultaneous Surface Functionalization of Ordered Mesoporous Carbon (FDU-15) by Wet Oxidation as a Promising Adsorbent [J].
Wu, Zhangxiong ;
Webley, Paul A. ;
Zhao, Dongyuan .
LANGMUIR, 2010, 26 (12) :10277-10286
[96]   3D interconnected mesoporous Si/SiO2 coated with CVD derived carbon as an advanced anode material of Li-ion batteries [J].
Xiao, Kuikui ;
Tang, Qunli ;
Liu, Zheng ;
Hu, Aiping ;
Zhang, Shiying ;
Deng, Weina ;
Chen, Xiaohua .
CERAMICS INTERNATIONAL, 2018, 44 (04) :3548-3555
[97]   Mesoporous Co3O4 and CoO@C Topotactically Transformed from Chrysanthemum-like Co(CO3)0.5(OH)•0.11H2O and Their Lithium-Storage Properties [J].
Xiong, Shenglin ;
Chen, Jun Song ;
Lou, Xiong Wen ;
Zeng, Hua Chun .
ADVANCED FUNCTIONAL MATERIALS, 2012, 22 (04) :861-871
[98]   Prussian blue and its derivatives as electrode materials for electrochemical energy storage [J].
Xu, Yuxia ;
Zheng, Shasha ;
Tang, Hanfei ;
Guo, Xiaotian ;
Xue, Huaiguo ;
Pang, Huan .
ENERGY STORAGE MATERIALS, 2017, 9 :11-30
[99]   Nanocatalytic Medicine [J].
Yang, Bowen ;
Chen, Yu ;
Shi, Jianlin .
ADVANCED MATERIALS, 2019, 31 (39)
[100]   Reactive Oxygen Species (ROS)-Based Nanomedicine [J].
Yang, Bowen ;
Chen, Yu ;
Shi, Jianlin .
CHEMICAL REVIEWS, 2019, 119 (08) :4881-4985