Synthesis and self-assembly properties of thiacrown-cyclized tetrathiafulvalene organogelators

被引：0
|
作者：
Hou, Ruibin [1 ,2 ]
Xu, Chao [1 ,2 ]
Yan, Jiajia [1 ,2 ]
Xia, Yan [1 ,2 ]
Li, Dongfeng [1 ]
机构：
[1] Changchun Univ Technol, Coll Chem & Life Sci, Changchun, Peoples R China
[2] Changchun Univ Technol, Adv Inst Mat Sci, Changchun, Peoples R China
来源：
JOURNAL OF SULFUR CHEMISTRY | 2023年 / 44卷 / 04期
基金：
中国国家自然科学基金;
关键词：
Tetrathiafulvalene; thiacrown ether; gelator; xerogel morphology; multiple stimuli responses; SUPRAMOLECULAR GELS; STIMULI-RESPONSIVENESS; HYBRID MATERIALS; POLYMER NETWORK; MONOPYRROLOTETRATHIAFULVALENE; DERIVATIVES; METAL; COMPLEX; GELATOR; ION;
D O I：
10.1080/17415993.2023.2175615
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel low-molecular-weight organogelator (1) based on thiacrown-cyclized tetrathiafulvalene has been synthesized through cross-coupling reaction of crown-fused 1,3-dithiole-2-one 3 and the thione 4 in the presence of triethyl phosphite. The molecular structure of 1 was fully characterized by nuclear magnetic resonance spectroscopy, matrix-assisted laser desorption/ionization time-of-flight mass spectrometry, and infrared spectroscopy. Gel-forming-ability experiments showed that the gelator could only form an opaque gel in dimethyl sulfoxide by sonication. The xerogel morphology observed by scanning electron microscopy showed an amorphous wrinkled structure. The gel exhibited varied responses to various external stimuli, including temperature, chemical oxidation, anions, and Na+ ions.
引用
收藏
页码：494 / 504
页数：11
相关论文
共 50 条
  • [31] Synthesis, Aggregation, Self-assembly, and Dynamic Properties of Helicene Oligomers
    Saito, Nozomi
    YAKUGAKU ZASSHI-JOURNAL OF THE PHARMACEUTICAL SOCIETY OF JAPAN, 2017, 137 (12): : 1483 - 1490
  • [32] Mesoporous hydroxyapatite: Synthesis in molecular self-assembly and adsorption properties
    Ma, Ke
    Cui, Haiwei
    Zhou, Annan
    Wu, Honghua
    Dong, Xiaolong
    Zu, Fenghua
    Yi, Jianjun
    Wang, Runwei
    Xu, Qinghong
    MICROPOROUS AND MESOPOROUS MATERIALS, 2021, 323
  • [33] Semiconducting Oligo-(Aryleneethynylene)s with Coplanarity of Main Chain and Tetrathiafulvalene (TTF) Side Chains: Synthesis, Self-Assembly, and Conductive Properties
    Hou, Yanhui
    Yang, Min
    Wan, Xiangjian
    Mao, Jie
    Ma, Yanfeng
    Huang, Yi
    Chen, Yongsheng
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2009, 210 (12) : 1044 - 1051
  • [34] Synthesis, self-assembly and magnetic properties of FePtCu anoparticles.
    Sun, XC
    Nikles, DE
    Li, J
    Wang, ZL
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2003, 225 : U513 - U513
  • [35] Design, modeling and synthesis of molecular tweezers with self-assembly properties
    Ghodratbeigi, Mohsen
    Rashidi-Ranjbar, Parviz
    Abbasi, Alireza
    JOURNAL OF MOLECULAR STRUCTURE, 2011, 990 (1-3) : 140 - 151
  • [36] Synthesis, self-assembly, and properties of Mn doped ZnO nanoparticles
    Barick, K. C.
    Bahadur, D.
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2007, 7 (06) : 1935 - 1940
  • [37] Synthesis, Physical Properties, and Self-Assembly of A Novel Asymmetric Aroyleneimidazophenazine
    Zhao, Jianfeng
    Wong, Jen It
    Wang, Chengyuan
    Gao, Junkuo
    Ng, Verena Zi Yun
    Yang, Hui Ying
    Loo, Say Chye Joachim
    Zhang, Qichun
    CHEMISTRY-AN ASIAN JOURNAL, 2013, 8 (03) : 665 - 669
  • [38] Synthesis, self-assembly and magnetic properties of FePtCu nanoparticle arrays
    Sun, XC
    Kang, SS
    Harrell, JW
    Nikles, DE
    THREE-DIMENSIONAL NANOENGINEERED ASSEMBLIES, 2003, 739 : 121 - 126
  • [39] Synthesis, electronic properties, and self-assembly of an alkylated dibenzo(biscorannulene)
    Kunioka, Natsumi
    Furukawa, Masazumi
    Hashimoto, Shingo
    Tahara, Kazukuni
    ORGANIC CHEMISTRY FRONTIERS, 2022, 9 (09) : 2509 - 2515
  • [40] Synthesis and self-assembly properties of peptide - Polylactide block copolymers
    Caillol, S
    Lecommandoux, S
    Mingotaud, AF
    Schappacher, M
    Soum, A
    Bryson, N
    Meyrueix, R
    MACROMOLECULES, 2003, 36 (04) : 1118 - 1124
12345