Three-Dimensional Visualization Reveals Pore-Scale Mechanisms of Colloid Transport and Retention in Two-Phase Flow

Colloids are ubiquitous in the natural environment, playing an important role in facilitating the transport of absorbed contaminants. However, due to the complexities arising from twophase flow and difficulties in three-dimensional observations, the detailed mechanisms of colloid transport and retention under twophase flow are still not well understood. In this work, we visualize the colloid transport and retention during immiscible two-phase flow based on confocal microscopy. We find that the colloid transport and retention behaviors depend strongly on the flow rate and pore/grain size. At low levels of saturation (high flow rate) with the wetting liquid mainly present as pendular rings, the colloids can aggregate at the liquid filaments in small-grain packings and are uniformly distributed in large-grain packings. Through theoretical analysis of the pendular ring geometry, we elucidate the mechanism responsible for the strong dependence of colloid clogging behavior on solid grain size. Our results further demonstrate that even at dilute concentrations, colloids can alter the flow paths and the wetting fluid topology, suggesting a strong two-way coupling dynamics between immiscible two-phase flow and colloid transport and calling for improved predictive models to incorporate the overlooked clogging behavior.