Formulation and characterization of polyester-lignite composite coated slow-release fertilizers

被引:15
作者
Abhiram, Gunaratnam [1 ,2 ]
Bishop, Peter [1 ]
Jeyakumar, Paramsothy [1 ]
Grafton, Miles [1 ]
Davies, Clive E. [3 ]
McCurdy, Murray [4 ,5 ]
机构
[1] Massey Univ, Sch Agr & Environm, Environm Sci, Private Bag 11 222, Palmerston North 4442, New Zealand
[2] Uva Wellassa Univ, Fac Anim Sci & Export Agr, Dept Export Agr, Badulla, Sri Lanka
[3] Massey Univ, Sch Food & Adv Technol, Private Bag 11 222, Palmerston North 4442, New Zealand
[4] Verum Grp, Lower Hutt, New Zealand
[5] GNS Sci, Lower Hutt, New Zealand
关键词
Calcium carbonate; Slow-release fertilizer; Lignite; Linseed oil; Polyester; BROWN-COAL; SOLUTE RELEASE; GROWTH; SOIL; WATER; SUPERABSORBENT; EPOXY;
D O I
10.1007/s11998-022-00670-6
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Two polyester-lignite composite coated urea slow-release fertilizers (SRFs; Poly3 and Poly5) were developed and their physicochemical properties were studied. Both these SRFs significantly (p < 0.05) extended the urea release compared to uncoated urea; Poly3 and Poly5 by 117 and 172 h, respectively. The urea release characteristics of Poly5 were further enhanced by linseed oil application (Poly5-linseed). The SEM images demonstrated the coatings were in contact with the urea and encase urea particles completely with the average coating thickness of 167.2 +/- 15 mu m. The new interactions between polyester and lignite in the composite coating were confirmed by the FTIR analysis. Polyester-calcium carbonate (Polyester-CaCO3) coated SRFs (Calc3 and Calc5) were developed using CaCO3 as a filler in place of lignite and the urea dissolution rate was compared with Poly3 and Poly5. The urea release times for the polyester-CaCO3 formulations, 48 and 72 h, were significantly (P < 0.05) lower than the polyester-lignite formulation, showing that lignite imparted greater control over release time than CaCO3. Findings from this work showed that polyester-lignite composites can be used as a coating material for SRFs. [GRAPHICS] .
引用
收藏
页码:307 / 320
页数:14
相关论文
共 42 条
[1]  
[Anonymous], 2021, International Fertilizer Industry Association (IFA)
[2]   Salt-controlled self-healing nanogel composite embedded with epoxy as environmentally friendly organic coating [J].
Atta, Ayman M. ;
Al-Lohedan, Hamad A. ;
El-Saeed, Ashraf M. ;
Al-Shafey, Hussin I. ;
Wahby, Mohamed .
JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, 2017, 14 (05) :1225-1236
[3]   Review on materials & methods to produce controlled release coated urea fertilizer [J].
Azeem, Babar ;
KuShaari, KuZilati ;
Man, Zakaria B. ;
Basit, Abdul ;
Thanh, Trinh H. .
JOURNAL OF CONTROLLED RELEASE, 2014, 181 :11-21
[4]   Which shape factor(s) best describe granules? [J].
Bouwman, AM ;
Bosma, JC ;
Vonk, P ;
Wesselingh, JHA ;
Frijlink, HW .
POWDER TECHNOLOGY, 2004, 146 (1-2) :66-72
[5]  
Bruschi ML, 2015, 5-Mathematical models of drug release. Strategies to modify the drug release from pharmaceutical systems, P63, DOI [10.1016/B978-0-08-100092-2.00005-9, DOI 10.1016/B978-0-08-100092-2.00005-9]
[6]   Core-shell Au@Pd nanoparticles with enhanced catalytic activity for oxygen reduction reaction via core-shell Au@Ag/Pd constructions [J].
Chen, Dong ;
Li, Chengyin ;
Liu, Hui ;
Ye, Feng ;
Yang, Jun .
SCIENTIFIC REPORTS, 2015, 5
[7]  
Dash S, 2010, ACTA POL PHARM, V67, P217
[8]   Use of Biogenic Silica in Porous Alginate Matrices for Sustainable Fertilization with Tailored Nutrient Delivery [J].
de Matos, Mailson ;
Mattos, Bruno D. ;
Tardy, Blaise L. ;
Rojas, Orlando J. ;
Magalhaes, Washington L. E. .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2018, 6 (02) :2716-2723
[9]   One-Pot Synthesis of Bio-Based Waterborne Polyester as UV-Resistant Biodegradable Sustainable Material with Controlled Release Attributes [J].
Dutta, Geeti Kaberi ;
Karak, Niranjan .
ACS OMEGA, 2018, 3 (12) :16812-16822
[10]   Sustainable coating material based on chitosan-clay composite and paraffin wax for slow-release DAP fertilizer [J].
El Assimi, Taha ;
Lakbita, Omar ;
El Meziane, Abdellatif ;
Khouloud, Mehdi ;
Dahchour, Abdelmalek ;
Beniazza, Redouane ;
Boulif, Rachid ;
Raihane, Mustapha ;
Lahcini, Mohammed .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2020, 161 :492-502