Solubility Measurement and Model Calculation of Fluorene in Six Binary Solvents from 288.15 to 328.15 K

被引：1

作者：

Shi, Yuanjun ^{[1
]}

Ren, Jianpo ^{[1
]}

Xiao, Yuntian ^{[1
]}

Jia, Lihong ^{[2
]}

Jia, Dingding ^{[1
]}

Wang, Huiqi ^{[1
]}

Yin, Qiuxiang ^{[1
,3
]}

Zhou, Ling ^{[1
]}

机构：

[1] Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China

[2] Beijing Union Univ, Coll Biochem Engn, Beijing 100023, Peoples R China

[3] Tianjin Univ, Coinnovat Ctr Chem & Chem Engn Tianjin, Tianjin 300072, Peoples R China

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2024年 / 69卷 / 03期

关键词：

LIQUID PHASE-EQUILIBRIUM; MIXTURES; ETHANOL; WATER; DERIVATIVES; T=283.15; BENZENE; ACID;

D O I：

10.1021/acs.jced.3c00570

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The solubility of fluorene in six binary solvents (o-xylene + methanol, o-xylene + ethanol, o-xylene + isopropyl alcohol, o-xylene + n-propanol, o-xylene + 2-butanol, and o-xylene + n-butanol) was determined through the gravimetry method over a temperature range of 288.15 to 328.15 K under 0.1 MPa. The results suggested that the solubility of fluorene increased with increasing temperature and the mass fraction of o-xylene in six chosen binary solvents. Moreover, the solubility data of fluorene was fitted by four mathematical models (the modified Apelblat model, the CNIBS/R-K model, the modified Apelblat-Jouyban-Acree model, and the NRTL model). The values of average relative deviation (ARD) of the four models were all proven to be less than 5%, which indicated that these mathematical models were appropriate to simulate the solubility data of fluorene in the six selected binary solvents.

引用

页码：1284 / 1298

页数：15

共 31 条

[1] MATHEMATICAL REPRESENTATION OF THERMODYNAMIC PROPERTIES - CARBAZOLE SOLUBILITIES IN BINARY ALKANE + DIBUTYL ETHER AND ALKANE + TETRAHYDROPYRAN SOLVENT MIXTURES [J].

ACREE, WE ;

MCCARGAR, JW ;

ZVAIGZNE, AI ;

TENG, IL .

PHYSICS AND CHEMISTRY OF LIQUIDS, 1991, 23 (01) :27-35

[2] Acidities of platinum(II) μ-hydroxo complexes bearing diphosphine ligands [J].

Anandhi, U ;

Sharp, PR .

INORGANIC CHEMISTRY, 2004, 43 (21) :6780-6785

[3] Solubilities of o-acetylsalicylic, 4-aminosalicylic, 3,5-dinitrosalicylic, and p-toluic acid, and magnesium-DL-aspartate in water from T = (278 to 348) K [J].

Apelblat, A ;

Manzurola, E .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1999, 31 (01) :85-91

[4] AIE-Active Fluorene Derivatives for Solution-Processable Nondoped Blue Organic Light-Emitting Devices (OLEDs) [J].

Feng, Xin Jiang ;

Peng, Jinghong ;

Xu, Zheng ;

Fang, Renren ;

Zhang, Hua-rong ;

Xu, Xinjun ;

Li, Lidong ;

Gao, Jianhua ;

Wong, Man Shing .

ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (51) :28156-28165

[5] COMPREHENSIVE THERMODYNAMIC STUDIES OF SEVEN AROMATIC-HYDROCARBONS [J].

FINKE, HL ;

MESSERLY, JF ;

LEE, SH ;

OSBORN, AG ;

DOUSLIN, DR .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1977, 9 (10) :937-956

[6]

Franck H.-G., 1963, Industrial and Engineering Chemistry, V55, P38, DOI DOI 10.1021/IE50641A006

[7] Opto-electronic properties of fluorene-based derivatives as precursors for light-emitting diodes [J].

Fratiloiu, Silvia ;

Fonseca, Sofia M. ;

Grozema, Ferdinand C. ;

Burrows, Hugh D. ;

Costa, Maria L. ;

Charas, Ana ;

Morgado, Jorge ;

Siebbeles, Laurens D. A. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (15) :5812-5820

[8] Solid-Liquid Phase Equilibrium of 2-Mercapto-1,3,4-thiadiazol in Pure Organic Solvents [J].

Gao, Xujie ;

Yu, Shuai ;

Wu, Guang ;

Cheng, Yan ;

Xue, Fumin .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2021, 66 (12) :4706-4713

[9] Solubility, thermodynamic modeling and Hansen solubility parameter of a new type of explosive in four binary solvents (benzene plus ethanol, n-propanol, n-butanol and isoamyl alcohol) from 283.15 K to 323.15 K [J].

Guo, Hao-qi ;

Li, Yong-xiang ;

Yang, Yu-lin ;

Li, Zi-yang .

JOURNAL OF MOLECULAR LIQUIDS, 2021, 328

[10] Solubility of Fluorene in Benzene, Chloroform, Acetone, 1-Propanol, Isobutanol, and Methylbenzene from (283 to 323) K [J].

Han, Ye ;

Wang, Zhanzhong .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2009, 54 (01) :148-149

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