Conversion of 5-hydroxymethylfurfural to furan-2,5-dicarboxylic acid by a simple and metal-free catalytic system

被引：0

作者：

Wang, Xue ^{[1
]}

Guo, Xinyuan ^{[2
]}

Wang, Xinmei ^{[2
]}

Li, Chi ^{[2
]}

Wang, Shanjun ^{[2
]}

Li, Han ^{[2
]}

Gao, Yan'an ^{[3
]}

Li, Yiying ^{[4
]}

Wang, Jinhui ^{[1
,5
]}

Xu, Huanjun ^{[2
,5
]}

机构：

[1] Harbin Med Univ, Coll Pharm, Dept Med Chem & Nat Med Chem, Harbin, Peoples R China

[2] Qiongtai Normal Univ, Sch Sci, Haikou 571127, Peoples R China

[3] Hainan Univ, Minist Educ Adv Mat Trop, Key Lab, Isl Resources, Haikou 570228, Peoples R China

[4] Hainan Med Univ, Coll Basic Med & Life Sci, Haikou, Peoples R China

[5] Qiongtai Normal Univ, Key Lab Child Cognit & Behav Dev Hainan Prov, Haikou, Peoples R China

来源：

RSC ADVANCES | 2023年 / 13卷 / 20期

基金：

中国国家自然科学基金; 海南省自然科学基金;

关键词：

2,5-FURANDICARBOXYLIC ACID; AEROBIC OXIDATION; BIOMASS; SUPPORT;

D O I：

10.1039/d3ra01104f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple and metal-free catalytic system composed of (NaOBu)-Bu-t/DMF and an O-2 balloon efficiently converted 5-hydroxymethylfurfural (5-HMF) to furan-2,5-dicarboxylic acid with an 80.85% yield. 5-HMF analogues and various types of alcohols were also transformed to their corresponding acids in satisfactory to excellent yield by this catalytic system.

引用

页码：13819 / 13823

页数：5

共 46 条

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