Photoaddition of Dicarboxylic Acid Esters, Derivatives of Heterocyclic Compounds and Acenaphthene to Fullerene C60

被引：0
|
作者：
Markin, G. V. [1 ]
Kozlova, E. A. [1 ]
Lopatin, M. A. [1 ]
Kuropatov, V. A. [1 ]
Belikov, A. A. [1 ]
Ketkov, S. Yu. [1 ]
机构：
[1] Russian Acad Sci, GA Razuvaev Inst Organometall Chem, Nizhnii Novgorod 603950, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2023年 / 93卷 / SUPPL 3期
关键词：
monosubstituted 1,9-dihydrofullerenes; photoreactions; carboxylic acid esters; bisarenechromium; ION-RADICAL SALTS; FUNCTIONALIZATION; COMPLEXES; CRYSTAL;
D O I：
10.1134/S1070363223160041
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
New possibilities of the photochemical addition to fullerene C(60)were demonstrated. Monosubstituted 1,9-dihydrofullerenes were obtained by irradiation of C(60)in the presence of homologues of thiophene, pyridine, and naphthalene as well as esters of glutaric, phthalic, succinic, adipic, pyridinedicarboxylic acids and N-alkyllactam. The HC60 moiety is bound to the hydrocarbon part of the organic fragment. The product of the methyl glutarate addition was reduced by bis(arene)chromium to give a new ion-radical salt.
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收藏
页码：S663 / S671
页数：9
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