Transformation of 5-hydroxymethylfurfural to 5-hydroxymethyl-2-furan carboxylic acid mediated by silver nanoparticles biosynthesized from Spartium junceum flower extract

被引:8
作者
Kargar, Pouya Ghamari [1 ]
Shafiei, Mohammad [2 ]
Bagherzade, Ghodsieh [1 ]
机构
[1] Univ Birjand, Dept Chem, Fac Sci, Birjand 97175615, Iran
[2] Birjand Univ Med Sci, Fac Pharm, Dept Med Chem, Birjand, Iran
关键词
5-HMF; HMFCA; Silver nanoparticles; Spartium junceum; AEROBIC OXIDATION; GREEN SYNTHESIS; LEAF EXTRACT; SELECTIVE OXIDATION; AG-NPS; CATALYST; ZNO; HMF; PRECURSOR; SBA-16;
D O I
10.1016/j.mtsust.2023.100622
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The central idea of this study is to develop a green, efficient, and simple method for producing silver nanoparticles (Ag NPs) using Spartium junceum flower extract. The extract contains phenolic hydroxyl and carbonyl functional groups that enhance the adsorption of silver ions and their subsequent reduction to Ag NPs in situ. The synthesis of Ag NPs using this method offers a new environmentally friendly approach that the prepared nanoparticles exhibit high catalytic activity in the conversion of 5-hydroxymethylfurfural (5-HMF) into the more valuable chemical 5-Hydroxymethyl-2-furan carboxylic acid (HMFCA). The study investigates the parameters for HMFCA synthesis, including solvent, reaction temperature, reaction time, catalyst amount, base, and oxidant, using Ag NPs. The Ag NPs was characterized by various techniques such as FESEM, XRD, TEM, UV-Vis, and DLS. The results demonstrated that under optimal conditions, a yield of 98 % for HMFCA and a conversion rate of 99 % for 5-HMF were achieved at a temperature of 40 degrees C and a reaction time of 1 h. Furthermore, our catalytic system exhibited the ability to be reused for at least 12 cycles.
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页数:9
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