Sustainable and reagent-free cathodic precipitation for high-efficiency removal of heavy metals from soil leachate*

Heavy metal pollution of soils has become a serious environmental problem. Soil washing with degradable reagents is an effective remediation technique of heavy metal pollution, and the generated leachate must be appropriately treated before discharge. However, the existing methods usually have the problems of large consumption of regents, high cost, and secondary pollution. This study proposed a reagent-free electrochemical precipitation method to remove mixed heavy metal ions extracted from soils by citrate using inert electrodes (IrO2-Ta2O5/Ti anode and graphite cathode). The results showed that the low potential of cathode led to the electrodeposition of Cd; the local alkaline environment provided by electro-mediated water reduction caused the hydrolytic precipitation of Zn and Pb; and the precipitation of Fe washed out from Fe-rich soil resulted in the coprecipitation of As on cathode surface. These combined cathodic precipitation processes decreased the concentrations of toxic heavy metals by over 99.4% after 12 h of electrolysis at 26 mA cm-2. The electrodes exhibited high stability after multiple successive cycles of reuse. The concentrations of As, Zn, Pb and Cd in the leachate decreased to below the limits of industrial wastewater discharge in each cycle, and those in soils could be reduced by 53.8%, 58.8%, 25.5%, and 70.2% at the initial concentrations of 1549, 1016, 310 and 50 mg kg-1, respectively. The heavy metal removal rate increased with increasing current density in the range of 0-52 mA cm-2. This work provides an efficient and sustainable method for the remediation of site soils polluted by mixed heavy metals.