Zinc Complexes Containing Substituted 1,10-Phenanthrolines as Ligands: Synthesis, Structure and Application as Initiators of ε-Caprolactone, Rac- and L-Lactides Polymerization

被引：0

作者：

Agaeva, M. U. ^{[1
,2
]}

Mankaev, B. N. ^{[1
,2
]}

Filippenko, V. I. ^{[2
]}

Lysenko, K. A. ^{[2
]}

Egorov, M. P. ^{[1
]}

Karlov, S. S. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia

[2] Lomonosov Moscow State Univ, Fac Chem, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2023年 / 93卷 / SUPPL 1期

基金：

俄罗斯科学基金会;

关键词：

zinc; ligand; phenanthroline; ring-opening polymerization; RING-OPENING POLYMERIZATION;

D O I：

10.1134/S1070363223140426

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Zinc complexes X2Zn(L) (X = Et, OAc, OC(O)CF3)) were synthesized in which 1,10-phenanthrolines containing substituents at positions 2, 4, 7, and 9 were used as bidentate ligand L. The structures of the complexes were confirmed by NMR spectroscopy and elemental analysis. The structures of three complexes were investigated by X-ray diffraction analysis. The complexes have been studied as initiators of epsilon-caprolactone, L- and rac-lactides polymerization.

引用

页码：S304 / S316

页数：13

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