Three coordination polymers with neutral lead halide chains

被引：1

作者：

Liu, Xi ^{[1
]}

Zhang, Xue-Chun ^{[1
]}

Shu, Si ^{[1
]}

Zhu, Yu-Shu ^{[1
]}

Huang, Kun -Lin ^{[1
]}

机构：

[1] Chongqing Normal Univ, Coll Chem, Chongqing Key Lab Green Synth & Applicat, Chongqing 401331, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2023年 / 554卷

基金：

中国国家自然科学基金;

关键词：

Coordination polymer; Crystal structure; Photoluminescence; DFT calculation; INORGANIC-ORGANIC MATERIALS; OPTICAL-PROPERTIES; CRYSTAL-STRUCTURE; HYBRID;

D O I：

10.1016/j.ica.2023.121566

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three novel coordination polymers (CPs), [Pb(bpbp)X2]n (X = Cl (1), Br (2), I (3), bpbp = 4,4 '-bis(4-pyridyl)-biphenyl), were synthesized via solvothermal synthesis method. The three CPs are isostructural complexes exhibiting 2D inorganic-organic layer structures with (4, 4) topology which are constructed by Bpbp ligands connecting neutral [PbX2]n chains. The results of photoluminescence experiments and DFT calculations indicate that both the conjugated Bpbp ligands and halide anions show important roles in the emission process of CPs, and halide anions may slightly tune the structures and luminescence properties of CPs.

引用

页数：5

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