Efficient NOx Reduction against Alkali Poisoning over a Self-Protection Armor by Fabricating Surface Ce2(SO4)3 Species: Comparison to Commercial Vanadia Catalysts

Resolving severe deactivation by alkali metals for selective catalytic reduction of NOx with NH3 (NH3-SCR) is challenging. Herein, surface Ce2(SO4)3 species as a self-protection armor originally exhibited antipoisoning of potassium over ceria-based catalysts. The self-protection armor was also effective for other alkali (Na), alkali-earth (Ca), and heavy (Pb) metals, considerably resolving the deactivation of ceria-based SCR catalysts in practical applications. The catalytic activity tests indicated that the presence of similar to 0.8 wt % potassium did not deactivate sulfated CeO2 catalysts, yet commercial V2O5-WO3/TiO2 catalysts almost lost the NOx conversions. Potassium preferably bonded with surface sulfates to form K2SO4 accompanied with the majority of surface Ce-2(SO4)(3) over sulfated CeO2 catalysts, but preferably coupled with active vanadia to generate inactive KVO3 species over V2O5-WO3/TiO2 catalysts. Such an active Ce-2(SO4)(3) species facilitated the adsorption and reactivity of NH3 and NOx, enabling ceria catalysts to maintain high catalytic efficiency in the presence of potassium. Conversely, the introduction of potassium into V2O5-WO3/TiO2 catalysts caused a considerable loss of surface acidity, hindering catalyst reactivity during the SCR reaction. The self-protection armor of Ce-2(SO4)(3) species may open a promising pathway to develop efficient ceria-based SCR catalysts with strong antipoisoning ability.