Cyclopentadienyl capped thorium(<sc>iv</sc>) porphyrinoid complex

被引:0
|
作者
Mangel, Daniel N. [1 ]
Brewster, James T. [1 ]
Juarez, Gabriel J. [1 ]
Lynch, Vincent M. [1 ]
Sessler, Jonathan L. [1 ]
机构
[1] Univ Texas Austin, Dept Chem, Austin, TX 78712 USA
关键词
D O I
10.1039/d3cc05283d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction between Th(iv) dipyriamethyrin dichloride and sodium cyclopentadienyl (Cp) results in the formation of a cyclopentadienyl capped thorium dipyriamethyrin complex, which to our knowledge represents the first expanded porphyrin f-element Cp complex.
引用
收藏
页码:1020 / 1022
页数:3
相关论文
共 50 条
  • [1] Photosubstitution and photoreduction of a diazido platinum(<sc>iv</sc>) anticancer complex
    Shi, Huayun
    Ward-Deitrich, Christian
    Ponte, Fortuna
    Sicilia, Emilia
    Goenaga-Infante, Heidi
    Sadler, Peter J.
    DALTON TRANSACTIONS, 2024, 53 (31) : 13044 - 13054
  • [2] Anticancer iridium(<sc>iii</sc>) cyclopentadienyl complexes
    Starha, Pavel
    INORGANIC CHEMISTRY FRONTIERS, 2025, 12 (03): : 897 - 954
  • [3] Synthesis, characterization and anticancer properties of an oxovanadium(<sc>iv</sc>)-sunitinib complex
    Robledo, German Lopez
    de la Parra, Lucia Santa Maria
    Jori, Khalil
    Scalese, Gonzalo
    Lopez, Jose Martin Ramallo
    Rodenak-Kladniew, Boris Emilio
    Leon, Ignacio Esteban
    Islas, Maria Soledad
    NEW JOURNAL OF CHEMISTRY, 2025, 49 (09) : 3456 - 3463
  • [4] Adsorption properties of M-UiO-66 (M = Zr(<sc>iv</sc>); Hf(<sc>iv</sc>) or Ce(<sc>iv</sc>)) with BDC or PDC linker
    Gonzalez, Diego
    Pazo-Carballo, Cesar
    Camu, Esteban
    Hidalgo-Rosa, Yoan
    Zarate, Ximena
    Escalona, Nestor
    Schott, Eduardo
    DALTON TRANSACTIONS, 2024, 53 (25) : 10486 - 10498
  • [5] Ru(<sc>iv</sc>)-Ru(<sc>iv</sc>), Ru(<sc>iii</sc>)-Ru(<sc>iv</sc>), and Ru(<sc>iii</sc>)-Ru(<sc>iii</sc>) complexes having a sulfato bridging ligand on the doubly oxido-/hydroxido-bridged core, and their crystallographic and electronic structures
    Misawa-Suzuki, Tomoyo
    Kataoka, Yusuke
    Mafune, Sota
    Niwa, Teresa
    Nagao, Hirotaka
    DALTON TRANSACTIONS, 2025, 54 (07) : 2937 - 2949
  • [6] Double complex salts based on tetraamminplatinum(<sc>ii</sc>) and vanadyl(<sc>iv</sc>) bisoxalate for the preparation of bimetallic Pt-V alloys
    Vorobyeva, Sofia N.
    Rudzis, Zakhar V.
    Sukhikh, Taisiya S.
    Filatov, Evgeny Yu.
    Plusnin, Pavel E.
    Nadolinny, Vladimir A.
    Bogomyakov, Artem S.
    Korenev, Sergey V.
    NEW JOURNAL OF CHEMISTRY, 2024, 48 (36) : 15894 - 15903
  • [7] Thorium(<sc>iv</sc>)-antimony complexes exhibiting single, double, and triple polar covalent metal-metal bonds
    Du, Jingzhen
    Dollberg, Kevin
    Seed, John A.
    Wooles, Ashley J.
    von Haenisch, Carsten
    Liddle, Stephen T.
    NATURE CHEMISTRY, 2024, 16 (05) : 780 - 790
  • [8] The crystal chemistry of plutonium(<sc>iv</sc>) borophosphate
    Sigmon, Ginger E.
    DiBlasi, Nicole A.
    Hixon, Amy E.
    DALTON TRANSACTIONS, 2023, 52 (45) : 16601 - 16606
  • [9] SOME NEW AMIDE AND SUBSTITUTED UREA COMPLEXES OF CYCLOPENTADIENYL THORIUM(IV) AND URANIUM(IV) CHLORIDES AND CYCLOPENTADIENYL THORIUM(IV)) BROMIDE
    ALDAHER, AGM
    BAGNALL, KW
    JOURNAL OF THE LESS-COMMON METALS, 1986, 116 (02): : 351 - 358
  • [10] Synthesis and reactivity of a uranium(<sc>iv</sc>) complex supported by a monoanionic nitrogen-phosphorus ligand
    Li, Kai
    He, Jialu
    Zhao, Yue
    Zhu, Congqing
    INORGANIC CHEMISTRY FRONTIERS, 2023, 10 (19): : 5622 - 5633