Feasibility Assessment on Remanufacturing of Ni-Mo/γ-Al2O3 Catalyst for Residue Hydrodesulfurization

被引:6
作者
Ahn, Seon-Yong [1 ]
Na, Woo-Jin [2 ]
Kim, Kyoung-Jin [1 ]
Kim, Beom-Jun [1 ]
Park, Hea-Kyung [2 ]
Roh, Hyun-Seog [1 ]
机构
[1] Yonsei Univ, Dept Environm & Energy Engn, 1 Yonseidae Gil, Wonju 26493, South Korea
[2] Hanseo Univ, Dept Mat Sci & Chem Engn, 46 Hanseo 1 Ro,Heami Myun, Seosan 31962, South Korea
关键词
remanufacturing; catalyst; residue hydrodesulfurization; sulfur removal; vanadium removal; petroleum refining; NIMO CATALYSTS; SPENT; DIBENZOTHIOPHENE; REGENERATION; GAMMA-AL2O3; PERFORMANCE; REDUCTION; STABILITY; RECOVERY;
D O I
10.3390/catal13040738
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Residue hydrodesulfurization (RHDS) is a critical process in the petroleum refining industry for removing sulfur compounds from heavy residual oils. However, catalysts used in RHDS can easily be deactivated by numerous factors, leading to reduced process efficiency and economic benefits. The remanufacturing of spent catalysts can be a useful strategy for extending the lifespan of catalysts, reducing waste, and improving process sustainability. This paper proposes an effective catalyst remanufacturing process for commercial RHDS catalysts. In detail, sequential unit processes including oil washing (OW), complete incineration (CI), and acid leaching (AL) were conducted to remanufacture the spent RHDS catalysts. We also highlight some of the key challenges in remanufacturing catalysts, such as the key factors involved in catalyst deactivation. Finally, we provide future perspectives on the development of an effective catalyst remanufacturing process for RHDS, with the goal of improving the efficiency, sustainability, and competitiveness of the petroleum refining industry.
引用
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页数:16
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共 55 条
[1]   Synthesis and Characterization of New nano catalyst Mo-Ni /TiO2- γAl2O3 for Hydrodesulphurization of Iraqi Gas Oil [J].
Ahmed, Dalya Jasim ;
Al-Abdaly, Basim Ibrahim ;
Hussein, Sattar Jalil .
BAGHDAD SCIENCE JOURNAL, 2021, 18 (04) :1557-1567
[2]   Unravelling the active sites and structure-activity relationship on Cu-ZnO-Al2O3 based catalysts for water-gas shift reaction [J].
Ahn, Seon-Yong ;
Kim, Kyoung-Jin ;
Kim, Beom-Jun ;
Shim, Jae-Oh ;
Jang, Won-Jun ;
Roh, Hyun-Seog .
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY, 2023, 325
[3]   CeO2-based oxygen storage capacity materials in environmental and energy catalysis for carbon neutrality: extended application and key catalytic properties [J].
Ahn, Seon-Yong ;
Jang, Won-Jun ;
Shim, Jae-Oh ;
Jeon, Byong-Hun ;
Roh, Hyun-Seog .
CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 2024, 66 (04) :1316-1399
[4]   A review of metal recovery from spent petroleum catalysts and ash [J].
Akcil, Ata ;
Veglio, Francesco ;
Ferella, Francesco ;
Okudan, Mediha Demet ;
Tuncuk, Aysenur .
WASTE MANAGEMENT, 2015, 45 :420-433
[5]   Recycling and Recovery Routes for Spent Hydroprocessing Catalyst Waste [J].
Al-Sheeha, H. ;
Marafi, Meena ;
Raghavan, Vira ;
Rana, Mohan S. .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2013, 52 (36) :12794-12801
[6]   Demonstration of the Influence of Specific Surface Area on Reaction Rate in Heterogeneous Catalysis [J].
Bernard, Pawel ;
Stelmachowski, Pawel ;
Bros, Pawel ;
Makowski, Waclaw ;
Kotarba, Andrzej .
JOURNAL OF CHEMICAL EDUCATION, 2021, 98 (03) :935-940
[7]   Characterization and Activity of ZrO2 Doped SBA-15 Supported NiMo Catalysts for HDS and HDN of Bitumen Derived Heavy Gas Oil [J].
Biswas, Piyali ;
Narayanasarrna, Prabhu ;
Kotikalapudi, Chandra Mouli ;
Dalai, Ajay K. ;
Adjaye, John .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2011, 50 (13) :7882-7895
[8]   Role of pore curvature on the thermal stability of gold nanoparticles in mesoporous silica [J].
Bore, MT ;
Pham, HN ;
Ward, TL ;
Datye, AK .
CHEMICAL COMMUNICATIONS, 2004, (22) :2620-2621
[9]   TEMPERATURE-PROGRAMMED REDUCTION OF NI-MO OXIDES [J].
BRITO, JL ;
LAINE, J ;
PRATT, KC .
JOURNAL OF MATERIALS SCIENCE, 1989, 24 (02) :425-431
[10]   Enhanced Catalytic Transfer Hydrogenation of Ethyl Levulinate to γ-Valerolactone over a Robust Cu-Ni Bimetallic Catalyst [J].
Cai, Bo ;
Zhou, Xin-Cheng ;
Miao, Ying-Chun ;
Luo, Jin-Yue ;
Pan, Hui ;
Huang, Yao-Bing .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2017, 5 (02) :1322-1331