Phosphoric acid-activated biochar derived from sunflower seed husk: Selective antibiotic adsorption behavior and mechanism

被引：95

作者：

Nguyen, Thi-Kim-Tuyen ^{[1
]}

Nguyen, Thanh-Binh ^{[1
]}

Chen, Wei-Hsin ^{[2
,3
,4
]}

Chen, Chiu-Wen ^{[1
,5
]}

Patel, Anil Kumar ^{[1
]}

Bui, Xuan-Thanh ^{[6
,7
]}

Chen, Linjer ^{[6
]}

Singhania, Reeta Rani ^{[1
]}

Dong, Cheng-Di ^{[1
,5
]}

机构：

[1] Natl Kaohsiung Univ Sci & Technol, Inst Aquat Sci & Technol, Kaohsiung 81157, Taiwan

[2] Natl Cheng Kung Univ, Dept Aeronaut & Astronaut, Tainan 701, Taiwan

[3] Tunghai Univ, Res Ctr Smart Sustainable Circular Econ, Taichung 407, Taiwan

[4] Natl Chin Yi Univ Technol, Dept Mech Engn, Taichung 411, Taiwan

[5] Natl Kaohsiung Univ Sci & Technol, Dept Marine Environm Engn, Kaohsiung 81157, Taiwan

[6] Ho Chi Minh City Univ Technol HCMUT, Vietnam Natl Univ Ho Chi Minh VNU HCM, Key Lab Adv Waste Treatment Technol, Ho Chi Minh City 700000, Vietnam

[7] Ho Chi Minh City Univ Technol HCMUT, Fac Environm & Nat Resources, 268 Ly Thuong Kiet St, Ho Chi Minh City 700000, Vietnam

来源：

BIORESOURCE TECHNOLOGY | 2023年 / 371卷

关键词：

Sunflower seed husk; Antibiotic; Adsorption; Biochar; H3PO4; BIOSORPTIVE UPTAKE; MAGNETIC BIOCHAR; TEA WASTE; REMOVAL; KINETICS; THERMODYNAMICS; IBUPROFEN; TETRACYCLINE; EQUILIBRIUM; SULFAMETHOXAZOLE;

D O I：

10.1016/j.biortech.2023.128593

中图分类号：

S2 [农业工程];

学科分类号：

0828 ;

摘要：

In recent years, the unnecessary overuse of antibiotics has increased globally, resulting in antibiotic contamination of water, which has become a significant environmental concern. This study aims to examine the adsorption behavior of antibiotics (Tetracycline TC, Ciprofloxacin CIP, Ibuprofen IBP, and Sulfamethoxazole SMX) onto H3PO4-activated sunflower seed husk biochar (PSF). The results demonstrated that H3PO4 could enhance the specific surface area (378.8 m2/g) and create a mesoporous structure of biochar. The adsorption mechanism was investigated using kinetic models, isotherms, and thermodynamics. The maximum adsorption capacities (qmax) of TC, CIP, SMX, and IBP are 429.3, 361.6, 251.3, and 251.1 mg g-1, respectively. The adsorption mechanism of antibiotics on PSF was governed by complex mechanisms, including chemisorption,

引用

页数：11

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