Thermal dynamics of gold nanoshell dimers under femtosecond laser pulse irradiation: A numerical approach

We present a numerical investigation of the photothermal response of gold nanoshell (AuNS) dimers when subjected to femtosecond laser pulse irradiation. The time-varying temperature fields for core-shell AuNS dimers are quantified by implementing finite element modeling, integrating the electromagnetic and thermal dual-physics simulations. Given the ultrafast nature of laser pulses, we employ a two-temperature model to accurately portray the energy transfer from excited electrons to the lattice system, a process typically completed post pulse-termination. The temporal analysis of the temperature in the AuNS and the surrounding medium, together with the spatial temperature distribution under different separation distances, elucidates the processes that drive the AuNS dimers' transient temperature distribution and heat dissipation. We report on the critical effects of geometrical parameters on the photothermal response, demonstrating that thinner shells maximize the total deposited energy per unit volume, resulting in increased temperature fields, while decreasing separation distances result in excessive field amplification due to plasmonic modes' production. Our robust numerical approach, enabling simulations with tunable material properties and configurations, may help design nanomaterials with desired features for photothermal cancer treatment and imaging.