Removal of Cd(II) Ions from Aqueous Solutions using adsorption By Bentonite Clay and Study the Adsorption Thermodynamics

被引:4
作者
Hammood, Ahmed Yosif [1 ]
Mohammed, Inas Kassim [1 ]
Majeed, Ahmed Abdalhadi [2 ,3 ]
机构
[1] Univ Basrah, Marine Sci Ctr, Dept Marine Environm Chem, Basrah, Iraq
[2] Al Ayen Univ, Sci Res Ctr, Thi Qar, Iraq
[3] Minist Educ Iraq, Educ Directorate Thi Qar, Thi Qar, Iraq
来源
POLLUTION | 2023年 / 9卷 / 03期
关键词
Adsorption; Bentonite; Cd(II) ions; Langmuir and; Freundlich models; Thermodynamic; CADMIUM(II) IONS; ACTIVATED CARBON; EFFICIENT; COMPOSITE; LEAD(II);
D O I
10.22059/poll.2023.353137.1741
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
cadmium usually enter the environment and water resources through wastewater, released by various industries, and may have adverse effects. The current study employs surface of bentonite clay available locally in order to remove cadmium In solutions contaminated with this type of ions, in order to research on a surface with a high ability to adsorption of cadmium (II) ions, study Some factors affect the adsorption process on bentonite clay, such as contact time, pH the solution, Adsorbent particle size, Initial concentration of solutions and temperature of the solution were examined in the a batch process mode. The amount of adsorbed Cd (II) increased with height temperature, the optimum adsorption pH was about 6.5. Under this condition, the percent removal was 95.17%. The adsorption isotherms were studied and the results of adsorption processes were more fitted with Friendlich model rather than Langmuir adsorption model. Thermodynamic study showed that, & UDelta;H was endothermic, & UDelta;G is found to be negative That is, the process is automatic and & UDelta;S was found to be positive. The current study also involves practical application using bentonite to get rid of Cd(II) ions to from wastewater of Hamdan's station of the Basra- iraq, The results indicate high affinity (97.84%) removal of Cd(II) ions.
引用
收藏
页码:994 / 1005
页数:12
相关论文
共 36 条
[1]   Experimental investigation of activated carbon prepared from apricot stones material (ASM) adsorbent for removal of malachite green (MG) from aqueous solution [J].
Abbas, Moussa .
ADSORPTION SCIENCE & TECHNOLOGY, 2020, 38 (1-2) :24-45
[2]   Removal of Cd(II), Cu(II), and Pb(II) by adsorption onto natural clay: a kinetic and thermodynamic study [J].
Abbou, Brahim ;
Lebkiri, Imane ;
Ouaddari, Hanae ;
Kadiri, Lamya ;
Ouass, Abdelkarim ;
Habsaoui, Amar ;
Lebkiri, Ahmed ;
Rifi, El Housseine .
TURKISH JOURNAL OF CHEMISTRY, 2021, 45 (02) :362-376
[3]  
Adamson A W., 2001, Physical Chemistry of Surfaces, V6th Ed
[4]   Synthesis of Activated Carbon from Sugarcane Bagasse and Application for Mercury Adsorption [J].
Alsadi, Javidi K. ;
Esfandiari, N. .
POLLUTION, 2019, 5 (03) :585-596
[5]   SYNTHESIS AND CHARACTERIZATION OF NANOCOMPOSITE NiFe2O4@SalenSi AND ITS APPLICATION IN EFFICIENT REMOVAL OF Ni(II) FROM AQUEOUS SOLUTION [J].
Babadi, Narjes ;
Tavakkoli, Haman ;
Afshari, Mozhgan .
BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA, 2018, 32 (01) :77-88
[6]   Heavy metal pollution in the environment and their toxicological effects on humans [J].
Briffa, Jessica ;
Sinagra, Emmanuel ;
Blundell, Renald .
HELIYON, 2020, 6 (09)
[7]  
Es-Said A., 2023, PHOSPHORUS SULFUR
[8]   Removal of Cadmium(II) and Lead(II) Ions from Aqueous Phase on Sodic Bentonite [J].
Gaona Galindo, Luz Stella ;
de Almeida Neto, Ambrosio Florencio ;
Carlos da Silva, Meuris Gurgel ;
Adeodato Vieira, Melissa Gurgel .
MATERIALS RESEARCH-IBERO-AMERICAN JOURNAL OF MATERIALS, 2013, 16 (02) :515-527
[9]   Microwave preparation of triethylenetetramine modified graphene oxide/chitosan composite for adsorption of Cr(VI) [J].
Ge, Huacai ;
Ma, Ziwei .
CARBOHYDRATE POLYMERS, 2015, 131 :280-287
[10]   Copper iodide decorated graphitic carbon nitride sheets with enhanced visible-light response for photocatalytic organic pollutant removal and antibacterial activities [J].
Ghanbari, Mojgan ;
Salavati-Niasari, Masoud .
ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY, 2021, 208