Highly efficient p-i-n perovskite solar cells that endure temperature variations

被引：319

作者：

Li, Guixiang ^{[1
]}

Su, Zhenhuang ^{[2
]}

Canil, Laura ^{[1
]}

Hughes, Declan ^{[3
]}

Aldamasy, Mahmoud H. ^{[1
]}

Dagar, Janardan ^{[1
]}

Trofimov, Sergei ^{[1
]}

Wang, Luyao ^{[1
]}

Zuo, Weiwei ^{[4
]}

Jeronimo-Rendon, Jose J. ^{[4
]}

Byranvand, Mahdi Malekshahi ^{[4
,5
]}

Wang, Chenyue ^{[2
]}

Zhu, Rui ^{[6
]}

Zhang, Zuhong ^{[6
]}

Yang, Feng ^{[6
]}

Nasti, Giuseppe ^{[7
]}

Naydenov, Boris ^{[1
]}

Tsoi, Wing C. ^{[3
]}

Li, Zhe ^{[8
]}

Gao, Xingyu ^{[2
]}

Wang, Zhaokui ^{[9
]}

Jia, Yu ^{[5
]}

Unger, Eva ^{[1
]}

Saliba, Michael ^{[4
,5
]}

Li, Meng ^{[1
,6
,8
]}

Abate, Antonio ^{[1
,7
]}

机构：

[1] Helmholtz Zentrum Berlin Mat & Energie GmbH, Hahn Meitner Pl 1, D-14109 Berlin, Germany

[2] Chinese Acad Sci, Shanghai Adv Res Inst, Shanghai Synchrotron Radiat Facil SSRF, 239 Zhangheng Rd, Shanghai 201204, Peoples R China

[3] Swansea Univ, Dept Mat Sci & Engn, SPECIFIC, Fac Sci & Engn, Bay Campus,Fabian Way, Swansea SA1 8EN, W Glam, Wales

[4] Univ Stuttgart, Inst Photovolta ipv, Pfaffenwaldring 47, D-70569 Stuttgart, Germany

[5] Forschungszentrum Julich, Helmholtz Young Investigator Grp FRONTRUNNER, IEK5 Photovolta, D-52425 Julich, Germany

[6] Henan Univ, Sch Mat Sci & Engn,Natl & Local Joint Engn Res Ct, Collaborat Innovat Ctr Nano Funct Mat & Applicat, Key Lab Special Funct Mat,Minist Educ, Kaifeng 475004, Peoples R China

[7] Univ Naples Federico II Naples, Dept Chem Mat & Prod Engn, Pzz Vincenzo Tecchio 80, I-80125 Naples, Italy

[8] Queen Mary Univ London, Sch Engn & Mat Sci SEMS, London E14NS, England

[9] Soochow Univ, Inst Funct Nano & Soft Mat FUNSOM, Jiangsu Key Lab Carbon Based Funct Mat & Devices, Suzhou 215123, Peoples R China

来源：

SCIENCE | 2023年 / 379卷 / 6630期

基金：

英国工程与自然科学研究理事会; 中国国家自然科学基金; 欧洲研究理事会;

关键词：

PERFORMANCE; INTERFACES;

D O I：

10.1126/science.add7331

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Daily temperature variations induce phase transitions and lattice strains in halide perovskites, challenging their stability in solar cells. We stabilized the perovskite black phase and improved solar cell performance using the ordered dipolar structure of beta-poly(1,1-difluoroethylene) to control perovskite film crystallization and energy alignment. We demonstrated p-i-n perovskite solar cells with a record power conversion efficiency of 24.6% over 18 square millimeters and 23.1% over 1 square centimeter, which retained 96 and 88% of the efficiency after 1000 hours of 1-sunmaximum power point tracking at 25 degrees and 75 degrees C, respectively. Devices under rapid thermal cycling between -60 degrees and +80 degrees C showed no sign of fatigue, demonstrating the impact of the ordered dipolar structure on the operational stability of perovskite solar cells.

引用

页码：399 / 403

页数：5

共 44 条

[1] 22.8%-Efficient single-crystal mixed-cation inverted perovskite solar cells with a near-optimal bandgap
Alsalloum, Abdullah Y.
Turedi, Bekir
Almasabi, Khulud
Zheng, Xiaopeng
Naphade, Rounak
Stranks, Samuel D.
Mohammed, Omar F.
Bakr, Osman M.
[J]. ENERGY & ENVIRONMENTAL SCIENCE, 2021, 14 (04) : 2263 - 2268
[2] Damp heat-stable perovskite solar cells with tailored-dimensionality 2D/3D heterojunctions
Azmi, Randi
Ugur, Esma
Seitkhan, Akmaral
Aljamaan, Faisal
Subbiah, Anand S.
Liu, Jiang
Harrison, George T.
Nugraha, Mohamad, I
Eswaran, Mathan K.
Babics, Maxime
Chen, Yuan
Xu, Fuzong
Allen, Thomas G.
Rehman, Atteq Ur
Wang, Chien-Lung
Anthopoulos, Thomas D.
Schwingenschlogl, Udo
De Bastiani, Michele
Aydin, Erkan
De Wolf, Stefaan
[J]. SCIENCE, 2022, 376 (6588) : 73 - +
[3] Halogen-Bonded Hole-Transport Material Suppresses Charge Recombination and Enhances Stability of Perovskite Solar Cells
Canil, Laura
Salunke, Jagadish
Wang, Qiong
Liu, Maning
Kobler, Hans
Flatken, Marion
Gregori, Luca
Meggiolaro, Daniele
Ricciarelli, Damiano
De Angelis, Filippo
Stolterfoht, Martin
Neher, Dieter
Priimagi, Arri
Vivo, Paola
Abate, Antonio
[J]. ADVANCED ENERGY MATERIALS, 2021, 11 (35)
[4] Tuning halide perovskite energy levels
Canil, Laura
Cramer, Tobias
Fraboni, Beatrice
Ricciarelli, Damiano
Meggiolaro, Daniele
Singh, Ajay
Liu, Maning
Rusu, Marin
Wolff, Christian M.
Nga Phung
Wang, Qiong
Neher, Dieter
Unold, Thomas
Vivo, Paola
Gagliardi, Alessio
De Angelis, Filippo
Abate, Antonio
[J]. ENERGY & ENVIRONMENTAL SCIENCE, 2021, 14 (03) : 1429 - 1438
[5] Design and understanding of encapsulated perovskite solar cells to withstand temperature cycling
Cheacharoen, Rongrong
Rolston, Nicholas
Harwood, Duncan
Bush, Kevin A.
Dauskardt, Reinhold H.
McGehee, Michael D.
[J]. ENERGY & ENVIRONMENTAL SCIENCE, 2018, 11 (01) : 144 - 150
[6] Quantum-size-tuned heterostructures enable efficient and stable inverted perovskite solar cells
Chen, Hao
Teale, Sam
Chen, Bin
Hou, Yi
Grater, Luke
Zhu, Tong
Bertens, Koen
Park, So Min
Atapattu, Harindi R.
Gao, Yajun
Wei, Mingyang
Johnston, Andrew K.
Zhou, Qilin
Xu, Kaimin
Yu, Danni
Han, Congcong
Cui, Teng
Jung, Eui Hyuk
Zhou, Chun
Zhou, Wenjia
Proppe, Andrew H.
Hoogland, Sjoerd
Laquai, Frederic
Filleter, Tobin
Graham, Kenneth R.
Ning, Zhijun
Sargent, Edward H.
[J]. NATURE PHOTONICS, 2022, 16 (05) : 352 - +
[7] Short-Chain Ligand-Passivated Stable α-CsPbI3 Quantum Dot for All-Inorganic Perovskite Solar Cells
Chen, Keqiang
Zhong, Qiaohui
Chen, Wen
Sang, Binghua
Wang, Yingwei
Yang, Tingqiang
Liu, Yueli
Zhang, Yupeng
Zhang, Han
[J]. ADVANCED FUNCTIONAL MATERIALS, 2019, 29 (24)
[8] Stabilizing perovskite-substrate interfaces for high-performance perovskite modules
Chen, Shangshang
Dai, Xuezeng
Xu, Shuang
Jiao, Haoyang
Zhao, Liang
Huang, Jinsong
[J]. SCIENCE, 2021, 373 (6557) : 902 - +
[9] Mixed 3D-2D Passivation Treatment for Mixed-Cation Lead Mixed-Halide Perovskite Solar Cells for Higher Efficiency and Better Stability
Cho, Yongyoon
Soufiani, Arman Mahboubi
Yun, Jae Sung
Kim, Jincheol
Lee, Da Seul
Seidel, Jan
Deng, Xiaofan
Green, Martin A.
Huang, Shujuan
Ho-Baillie, Anita W. Y.
[J]. ADVANCED ENERGY MATERIALS, 2018, 8 (20)
[10] Interfacial toughening with self-assembled monolayers enhances perovskite solar cell reliability
Dai, Zhenghong
Yadavalli, Srinivas K.
Chen, Min
Abbaspourtamijani, Ali
Qi, Yue
Padture, Nitin P.
[J]. SCIENCE, 2021, 372 (6542) : 618 - +

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